Abstract
The electro-oxidation of isosafrole on a smooth platinum electrode was investigated in the non-aqueous solution. The CV curve shows two oxidation peaks and one reduction peak in the potential region between -0.5 V and 1.95 V. The relation between the oxidation and reduction peaks has been determined also by CV. The adsorption behavior of isosafrole on Pt was also investigated.
Keywords
Isosafrole, Non-aqueous system, Cyclicvoltammetry, Pt electrode
Publication Date
2004-05-28
Online Available Date
2004-05-28
Revised Date
2004-05-28
Received Date
2004-05-28
Recommended Citation
Xiao-hong ZHANG.
Investigation of Adsorption and Oxidation Behavior of Isosafrole on a Smooth Pt[J]. Journal of Electrochemistry,
2004
,
10(2): 229-234.
DOI: 10.61558/2993-074X.1570
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol10/iss2/16
References
[1] ZHANGXiao hong(张小红),ZHANGLei(章磊),XIAOZhuan quan(肖转泉).Thesynthesisofisosafroleandstructuralanalysis[J].JiangxiChemicalIndustry,2001,1:23~25.
[2] CHENXiao yuan(陈小原),LUOGuang yan(罗光炎),YANGXiang zao(杨祥早),etal.Theisomerizationofsafroleandtheelectricoxidativesynthesisofpepperaldehyde[J].ChemicalandIndustryofForestProducts,1991,4(11):319~323.
[3] LIGuo zhi(李国智),ZHAOJi shou(赵吉寿),YANLi(颜莉).Theinvestigationofisosafroleoxidizedtopiperonal[J].JournalofYunnanNationCollege,1995,4(2):53~55.
[4] YANGGen fu.Thereactionconditioninvestigationofpiperonalusingozone[J]J.Guangzhouchemicalindustry,1991,34(2):17~23.
[5] TorriS,UneyamaK,UedaK.Electrochemicalprocedureforapracticalpreparationofpiperoanlfromisosafrole[J].J.Org.Chem,1984,49:1830~1832.
[6] JamesGrimshaw,ChengHua.Theconversionofisosafroletopeperonalandanetholetoanisaldehyde:electrochemicalicalactivemanganesedioxide[J].J.ElectrochimicaActa,1994,39:497~499.
[7] HUANGChao(黄超),JIYan guang(纪延光),ZHOUHong xun(周鸿勋).Theoptimalelectroanalysisconditionofpiperonal[J].J.JiangsuChemicalIndustry,1997,25(2):24~27.
[8] ZantaCLPS,A.R.deAndrade,BoodtsJFC.Electrochemicalbehaviorofolefins:oxidationatruthenium titaniumdioxideandiridium titaniumdioxidecoatedelectrodes[J].J.AppliedElectrochemistry,2000,30,467~474.
[9] ZHANGQing song(张清松),ZHANJian(占剑),WUHui huang(吴辉煌.).Theelectrooxidationofphenol[J].J.OrganicChemistryandIndustrialCommunication,1999,3:6~7.
[10] LINHeng(林珩),CHENSheng pei(陈声培),LINJin mei(林进妹),etal.AnEQCMStudyofWateradsorptionandQxidationonPtelectrodesinsulfateacidsolutions.[J].Electrochemistry,2003,9(1):47~53.
Included in
Catalysis and Reaction Engineering Commons, Engineering Science and Materials Commons, Materials Chemistry Commons, Materials Science and Engineering Commons, Physical Chemistry Commons, Power and Energy Commons