Abstract
A novel BaFeSi/C composite was prepared by mechanical ball milling, and lithium insertion reactions on the composite electrode were investigated by cyclic voltammetry ,charge-discharge measurements, XRD and XPS spectroscopy. It is demonstrated that the capacity retention with indiscernible capacity decas during charge-discharge cycling. The improved cycling ability of the composite is suggested from a cooperative action by inactive FeSi_(2 )and BaSi_2 matrix and outer graphite shell, which both buffer the volumetric changes of the active Si phase and provide a good connection for electronic and ionic conduction during lithium insertion and extraction processes.
Keywords
BaFeSi/C composite, Mechanical ball milling, Anode materials
Publication Date
2004-11-28
Online Available Date
2004-11-28
Revised Date
2004-11-28
Received Date
2004-11-28
Recommended Citation
Rui-xiang FENG, Hua DONG, Xin-ping AI, Han-xi YANG.
The Investigation of BaFeSi/C Alloy Composite as Anode Materials for Li-ion Battery[J]. Journal of Electrochemistry,
2004
,
10(4): 391-396.
DOI: 10.61558/2993-074X.1591
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol10/iss4/4
Included in
Engineering Science and Materials Commons, Materials Chemistry Commons, Materials Science and Engineering Commons, Physical Chemistry Commons, Power and Energy Commons
