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Corresponding Author

Zong-qing HUANG

Abstract

In electrochemical system, the mass transport process in liquid layer adjacent to electrode is studied through theoretical analysis only.The diffusion process can be analyzed theoretically by Fick's law for homogeneous media. Up to now, none of satisfied experimental method has been reported for studying mass transport of a whole process in liquid media yet. This paper described the experimental approach to explore mass transport in electrochemical system by transmission Vop-spectroellipsometry briefly.

Keywords

Optical tracking rate (Vop), Vop-spectroellipsometry

Publication Date

2004-11-28

Online Available Date

2004-11-28

Revised Date

2004-11-28

Received Date

2004-11-28

References

[1] HuangZQ,OrdJL.Anopticalstudyofironelectrodeinalkalineelectrolyte[J]J.Electrochem,Soc.,1985,132:24~29.
[2] HuangZQ,XieSF,ZhangST.ProgressofthenewapproachofSpectroellipsometryforstudyingelectrochemistry[J].TheElectrochemicalSocietyExtendedAbstracts,1994,(1):858.
[3] HuangZQ,Zhuw,YangYR.Vop-spectroellipsometryanditsapplicationinelectrochemistryandsolutionchemistry[J].ibid.,2003,(1):2622.
[4] HuangZQ,ZhuW,YangYR,Explorationanddiscoveryofanewapproachforstudyingmasstransportinliquidmedia[J].ibid.,2004,(1):2004.
[5] TaoCY,ZhangST,HuangZQ,etal.Studyonelectrochemicalreactionswithgrazeellipsometry[J].J.ChongqingUniv.,1998,21(2):40~45.
[6] HuangZQ,ZhuW,XieSF,etal.,Anewapproachforstudyingelectrodeprocessthroughmeasuringellipsometricparametersofliquidadjacenttotheelectrode[J].TheElectrochemicalSocietyExtendedAbstracts,2002,(1):1323.
[7] LiNB,TaoCY,ZhangST,etal.StudyonpropertiesofsurfacesolutionlayerofK4[Fe(CN)6]/K3[Fe(CN)6]withgrazeellipsometry[J].ActaPhysico-ChimicaSinica,1998,14(7):654~658.

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