•  
  •  
 

Abstract

The AAO template with nano-channels was synthesized and filled with transient metal-oxide NiO by sol-gel method, and their electrochemical properties were primarily studied. The results showed that the porous nano-channels were well defined with the diameter about 50nm. The nano-structured NiO was filled into the template's nano-channels successfully., Cyclic voltammetry studies show that the NiO in AAO template has good cycle stability.It was suggested that the AAO-metal-oxides composites could be used as novel anode materials for Lithium ion battery.

Keywords

AAO template, Nano-sized, NiO

Publication Date

2005-02-28

Online Available Date

2005-02-28

Revised Date

2005-02-28

Received Date

2005-02-28

References

[1] FertA,PirauxL.Magneticnanowires[J].JournalofMagnetismandMagneticMaterials,1999,200:338~358.
[2] LueJT.Areviewofcharacterizationandphysicalprop ertystudiesofmetallicnanoparticles[J].J.Phys.Chem.Solids,2001,62:1599~1612.
[3] BanfiG,DegiorgioV,RicardD.Nonlinearopticalpropertiesofsemiconductornanocrystals[J].Adv.Phys.,1998,47:447~510.
[4] PoizotP,LaruellS,GrugeonS, etal.Nano sizedtra nns metaloxidesasnegative electrodematerialsforlith ium ionbatteries[J].Nature,2000,407:496~499.
[5] ZhaoJ,GaoQY,GuC, etal.Preparationofmulti wallscarbonnanotubearrayelectrodesanditselectro chemicalintercalationbehaviorofLiions[J].ChemicalPhysicsLetters,2002,358(1~2):77~82.
[6] LaruelleS,GrugeonS,PoizotP, etal.OntheoriginoftheextraelectrochemicalcapacitydisplayedbyMO/Licellsatlowpotential[J].JournalofTheElectrochemi calSociety,2002,149(5):A627~A634.
[7] BadwayF,PlitzI,GrugeonS, etal.MetaloxidesasnegativeelectrodematerialsinLi ioncells[J].Electro chemicalandSolidStateLetters,2002,5(6):A 115~A118.
[8] PoizotP,LaruelleS,GrugeonS, etal.Rationalizationofthelow potentialreactivityof3d metal basedInorgan iccompoundstowardsLi[J].J.Electrochem.Soc.,2002,149(9):A1212~A1217.
[9] LiH,HuangXJ,ChenLQ.Anodebasedonoxidematerialsforlithiumrechargeablebatteries[J].SolidStateIonics,1999,123:189~197.
[10] BesenhardJO,WinterM.Advancesinbatterytech nology: rechargeablemagnesiumbatteriesandnovelnegative electrodematerialsforlithiumionbatteries[J].Chemphyschem,2002,3:155~159.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.