Abstract
Recent research development in molten salt electrochemistry at the Electrochemical Research Centre of Wuhan University is briefly reviewed. Attention is first paid on the preparation of silicon and its binary alloys, as well as oxide based functional materials. In addition, the quartz sealed Ag/AgCl reference electrodes suitable for high temperature molten salts are described. Focus is also given to two types of metal based cavity electrodes that are capable of loading micrograms of oxide powders and hence allow fast and reproducible measurements for the electrochemical behaviour of the powders in molten salts. The article finishes by highlighting the concept of “three-phase interline electrochemistry” in conjunction with reporting the preliminary results from the investigation of a simple "thin layer model" for the electrochemical reduction of solid AgCl in aqueous solution and solid SiO_(2)in molten salts.
Keywords
Molten salt electrochemistry, Silicon, Reference electrode, Cavity electrode, Three-phase interline electrochemistry
Publication Date
2005-05-28
Online Available Date
2005-05-28
Revised Date
2005-05-28
Received Date
2005-05-28
Recommended Citation
Di-hua WANG, Zheng CHEN.
Innovation in Molten Salt Electrochemistry[J]. Journal of Electrochemistry,
2005
,
11(2): 119-124.
DOI: 10.61558/2993-074X.1625
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol11/iss2/1
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