A Conjugate Dissolution / Deposition Behavior in Thin Layer Electrodeposition

Authors

SUN Bin, *, 1), ZOU Xian-wu~(2),JIN Zhun-zhi~(2)(1. Department of Materials and Chemical Engineering, Zhongyuan Institute of Technology, Zhengzhou 450007, China,2. School of Physics and Technology, Whuhan Uniiversity, Wuhan 430072,China;

Abstract

During the electrodeposition of lead, the dendrite deposit segregates from the cathode due to the disturbance of hydrogen gas. The segregated deposit could move toward the anode spontaneously rather than keep stationary. The studies show that this novel phenomenon was caused by the conjugate electrodissolution and electrodeposition reactions taking place at two ends of the isolated segment of the deposit. The mechanism inducing this phenomenon is suggested.

Keywords

Lead, Electrodeposition, Electrodissolution

DOI Link

https://doi.org/10.61558/2993-074X.1659

Publication Date

2005-08-28

Online Available Date

2005-08-28

Revised Date

2005-08-28

Received Date

2005-08-28

Recommended Citation

SUN Bin. A Conjugate Dissolution / Deposition Behavior in Thin Layer Electrodeposition[J]. Journal of Electrochemistry, 2005 , 11(3): 308-313.
DOI: 10.61558/2993-074X.1659
Available at: https://jelectrochem.xmu.edu.cn/journal/vol11/iss3/13

References

[1]Zach M P,Ng K H,PennerR M.Molybdenumnanow ires by electrodeposition[J].Sc ience,2000,290:2 120~2 122.
[2]Snyder G J,L im J R,Huang C K,et al.Thermoelectricm icrodevice fabricated by a MEMS-like electrochem i-cal process[J].Nature M aterials 2003,(2):528~530.
[3]Che G L,Lakshm i B B,F isher E R,et al.Carbon nano-tubu le m embranes for electrochem ical energy storageand production[J].Nature,1998,393:346~348.
[4]M arshall G,Mocskos E,Molina F V,et al.Buoyancyand electrically driven convection models in th in-layerelectrodeposition[J].Phy.Rev.E,2003,68:021 607.
[5]X ie Y W,Chen T,Dong S J.Influence on the th in lay-er spectroelectrochem istry:d iffusion w ith in a th in lay-er cell[J].E lectroch im.Acta,1995,40:1 177~1 180.
[6]W angM,Zhong S,Y in X B,et al.Spontaneous correla-tion of crystallograph ic orientations in crystallite ag-gregation[J].Phys.Rev.Lett.,2001,86:3 827~3 829.
[7]Futerko P,Hsing I M.Two-d im ensional fin ite-elem entm ethod study of the resistance of m embranes in poly-m er electrolyte fuel cells[J].E lectroch im.Acta,2000,45:1 741~1 747.
[8]M accallum J R,V incent C A.Polym er E lectrolyte Re-views 1[M].London:E lsevier,1987.
[9]C.A.V incentw ith F.Bon ino,M.lazzari and B.Scro-sati,Modern Batteries[M].London:Edward Arnold,1984.
[10]Chen Ti-xian,Experim ental E lectrochem istry[M].X iam en:X iam en Un iversity press,1993.
[11]Sun B(孙斌),Zou X(邹宪武),Jin Z Z(金准智).Morphological evolution in the electrodeposition of thePb-Sn b inary system[J].Physics Review E,2004,69:067202.
[12]Lee J K,Shem ilt LW,Chun H S.Stud ies of b ipolarityin flu id ized bed electrodes[J].J.App l.E lectro-chem.,1989,19:877~882.
[13]B rad ley J C,Chen H M,Crawford.J,et al..Creatingelectrical contacts between m etal partic les using d i-rected electrochem ical growth[J].Nature,1997,389:268~270.
[14]Zhou Shao-m in(周绍民).M etal E lectrodeposition-theroy and Study M ethods[M].Shanghai:ShanghaiSc ientific and Technological Press,1989.
[15]Kusakabe K,K imura T,Morooka S,et al.Rec ircu lat-ing feed operation of b ipolar packed-bed and trikle-bed electrode cells equ ipped w ith m esh spacers[J].J.App l.E lectrochem.,1987,17:724~729.
[16]Sm ithells C J.M etal Reference Book,5 th ed[M].London:Butterworths,1976.
[17]Zhang Ting-fang,Lu Jia-xing.E lectrolyte Solution[M].Shanghai:Shanghai Sc ientific and Technologi-cal L iterature Press,1991.
[18]Gonzalez G.,M arshall G.,Molina F,et al.Three-d i-m ensional nature of ion transport in th in-layer electro-deposition[J].Phys.Rev.E,2002,65:051 607.