Abstract
The accelerated dissolution behavior of Cu-Ni alloy induced by AFM tip scratching and the inhibition effect of corrosion inhibitors were investigated. The results showedthat, with a tip loading of 750nN ,continuous scan for 30 min in a contact mode on 4×4 μm~(2) of copper-nickel alloy in 1.5mol/L NaCl and 0.01mol/L HCl could enhance the dissolution of the sample and produced pits on the scratched area. Adding inorganic inhibitors, sodium chromateand organic inhibitor dodecylamine, to the solution suppressed the dissolution of copper-nickel alloyinduced by tip scratching, respectively, by improving the surface passivationperformance of metal surface and forming adsorption films on copper-nickel alloy.
Keywords
AFM tip scratching, Enhanced dissolution, Dodecylamine, Sodium chromate
Publication Date
2005-08-28
Online Available Date
2005-08-28
Revised Date
2005-08-28
Received Date
2005-08-28
Recommended Citation
Jun-e QU, Xing-peng GUO.
Investigation, on the Accelerated Dissolution of Metal Induced by AFM Tip Scratching and Suppressed by Inhibitors[J]. Journal of Electrochemistry,
2005
,
11(3): 319-323.
DOI: 10.61558/2993-074X.1661
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol11/iss3/15
Included in
Analytical Chemistry Commons, Materials Chemistry Commons, Nanoscience and Nanotechnology Commons, Physical Chemistry Commons
