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Corresponding Author

Jun GAO(yyang@xmu.edu.cn)

Abstract

The MnO2/C composite was synthesized by reduction of KMnO4 with acetylene black.The products were characterized by XRD and SEM.We used MnO2/C composite as the positive electrode material of the electrochemical capacitor.The performance of faradic psedocapacitance of the MnO2/C electrode was studied in different electrolytes.The MnO2/C electrode was tested by cyclic voltammetry,electrochemical impedance spectroscopy(EIS) and constant charge-discharge curves.The experimental results showed that the MnO2/C composite has excellent performance.The specific capacitance of the MnO2/C composite as 258 F/g is obtained at 5mA/cm2 current density in 1mol/L KOH solution.It exhibited high discharge capacity and good cycle performance.

Keywords

electrochemical capacitor, MnO2/C composite, specific capacitance

Publication Date

2007-08-28

Online Available Date

2007-08-28

Revised Date

2007-08-28

Received Date

2007-08-28

References

[1]Conway B E.Electrochemical supercapacitors[M].New York:Kluwer Academic/Plenum Publishers,1999.
[2]Xu C L,Bao S J,Kong L B,et al.Highly orderedMnO2nanowire array thin films on Ti/Si substrate as anelectrode for electrochemical capacitor[J].J of SolidState Chemistry,2006,179:1351-1355.
[3]Broughton J N,Brett M J.Variations in MnO2electro-deposition for electrochemical capacitors[J].Electro-chimica Acta,2005,50:4814-4819.
[4]Prasad K R,Miura N.Electrochemically synthesizedMnO2-based mixed oxides for high performance redoxsupercapacitors[J].Electrochemistry Communications,2004,6:1004-1008.
[5]Reddy R N,Reddy R G.Synthesis and electrochemicalcharacterization of amorphous MnO2electrochemical ca-pacitor electrode material[J].J of Power Sources,2004,132:312-320.
[6]Zhang Bao-hong(张宝宏),Zhang Na(张娜).Researchon nanophase MnO2for electrochemical supercapacitor[J].Acta Phys Chim Sin(in Chinese),2003,19(3):286-288.
[7]Zhang Zhi-an(张治安),Yang Bang-chao(杨邦朝),Deng Mei-gen(邓梅根),et al.Capacitive characteris-tics of amorphous MnO2/carbon black nanocomposite e-lectrode for supercapacitor[J].Journal of The ChineseCeramic Society(in Chinese),2005,33(2):164-169.
[8]Huang X K,Yue H J,Attia A,et al.Preparation andproperties of manganese oxide/carbon composites by re-duction of potassium permanganate with cetylene black[J].J of the Electrochemical Society,2007,154(1):A26-A33.

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