Studies on Catalytic Mechanism of Li/SOCl_2 Batteries by Metal Phthalocyanine Complexes

Authors

Zhan-wei XU, Shaanxi Key Laboratory of Physico-Inorganic Chemistry,Department of Chemistry, Northwest University,Xi'an,710069,China,;
Qing-jin SUN, Shaanxi Key Laboratory of Physico-Inorganic Chemistry,Department of Chemistry, Northwest University,Xi'an,710069,China,;
Bi-yun SU, Shaanxi Key Laboratory of Physico-Inorganic Chemistry,Department of Chemistry, Northwest University,Xi'an,710069,China,;
Tu-lin CHE, Shaanxi Key Laboratory of Physico-Inorganic Chemistry,Department of Chemistry, Northwest University,Xi'an,710069,China,;
Yan-hong SONG, Shaanxi Key Laboratory of Physico-Inorganic Chemistry,Department of Chemistry, Northwest University,Xi'an,710069,China,;
Yao-min LI, P.O.Box 121,Xi'an,710065,China;
Jian-she ZHAO, Shaanxi Key Laboratory of Physico-Inorganic Chemistry,Department of Chemistry, Northwest University,Xi'an,710069,China,;

Corresponding Author

Jian-she ZHAO

Abstract

Effects of metal phthalocyanine comlexes MPc(M= Mn(Ⅱ),Fe(Ⅱ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ)) as electrochemical catalysts on the performance of Li/SOCl2 batteries have been examined at constant resistance.And the reasons of MPc affecting the discharged voltage and discharged time of Li/SOCl2 batteries were also brought forward.A few new viewpoints on the catalytic mechanism of the reduction of thionyl chloride by phthalocyanine complexes were proposed.

Keywords

transition metal, phthalocyanine complexes, lithium/thionyl chloride, catalytic mechanism

DOI Link

https://doi.org/10.61558/2993-074X.1825

Publication Date

2007-08-28

Online Available Date

2007-08-28

Revised Date

2007-08-28

Received Date

2007-08-28

Recommended Citation

Zhan-wei XU, Qing-jin SUN, Bi-yun SU, Tu-lin CHE, Yan-hong SONG, Yao-min LI, Jian-she ZHAO. Studies on Catalytic Mechanism of Li/SOCl_2 Batteries by Metal Phthalocyanine Complexes[J]. Journal of Electrochemistry, 2007 , 13(3): 293-296.
DOI: 10.61558/2993-074X.1825
Available at: https://jelectrochem.xmu.edu.cn/journal/vol13/iss3/13