Corresponding Author

Jian-she ZHAO


Effects of metal phthalocyanine comlexes MPc(M= Mn(Ⅱ),Fe(Ⅱ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ)) as electrochemical catalysts on the performance of Li/SOCl2 batteries have been examined at constant resistance.And the reasons of MPc affecting the discharged voltage and discharged time of Li/SOCl2 batteries were also brought forward.A few new viewpoints on the catalytic mechanism of the reduction of thionyl chloride by phthalocyanine complexes were proposed.


transition metal, phthalocyanine complexes, lithium/thionyl chloride, catalytic mechanism

Publication Date


Online Available Date


Revised Date


Received Date



[1]WANG Yingche(王莹澈),CAI Shengtong(蔡圣同).The application and prospect of lithium reserve batteryin fuze power source[J].Journal of Detection&Control,2000,22(4):45-48.
[2]LIU Jing(刘景),GE Honghua(葛红花),ZHOUGuoding(周国定),et al.Research status of lithium/thionyl chloride battery[J].Battery,135(15):408-410.
[3]XU Zhanwei(许占位),SU Biyun(苏碧云),SONGYanhong(宋艳虹),et al.Research status of lithium/thionyl chloride battery cathode[C].In:Proceedings ofthe 4th National Physic-Inorganic Symposium.Linfen:Shanxi Normal University Press,2006.198-199.
[4]GUO Bingkun(郭炳焜),LI Xinhai(李新海),YANGSongqing(杨松青).Chemical cell principle&technol-ogy of cell[M].Changsha:Central South UniversityPress,2000.309-311.
[5]Lee S B,Pyun S I,Lee E J.Effect of the compactnessof the lithium chloride layer formed on the carbon cath-ode on the electrochemical reduction of SOCl2electrolytein Li/SOCl2batteries[J].Electrochimica Acta,2001,47(6):855-864.
[6]Doddapaneni N.Low-temperature performance of high-rate lithium/thionyl chloride cells[C]//In:Proceed-ings of the 30th Power Sources Symposium,Atlantic:NJ,1982,169-171.
[7]Bernstein P A,Lever A B P.Two electron oxidation ofcobalt phthalocyanines by thionyl chloride:implicationsfor lithium/thionyl chloride batteries[J].Inorg Chem,1990,29:608-612.
[8]Abraham K M,Alamgir M,Willstaedt E B,et al.Met-al phthalocyanine-catalyzed lithium/thionyl chloridecells[J].Electrochim Acta,1992,37(3):531-535.
[9]SHEN Yongjia(沈永嘉).The Syntheses and applica-tion of phthalocyanines[M].Beijing:Chemical Indus-try Press,1999.36-39.



To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.