•  
  •  
 

Abstract

The electrochemical behavior of luteolin was studied by voltammetry at a glassy carbon electrode in phosphate buffer solution.The results exhibited that the well-defined redox peak of luteolin is observed and the electrode process is adsorption-controlled.The charge transfer coefficient(α) was calculated as 0.66 in phosphate buffer solution(pH 4.0).The relationships between oxidation peak current and the concentration of luteolin are linear in the range of 1.0×10-8 ~ 5.0×10-6 mol·L-1 by differential pulse voltammetric method.The detection limit had been estimated as 1.0×10-8 molL-1.This method can be used for the determination of luteolin with satisfactory results.

Keywords

luteolin, glassy carbon electrode, flavonoids, voltammetry

Publication Date

2007-11-28

Online Available Date

2007-11-28

Revised Date

2007-11-28

Received Date

2007-11-28

References

[1]Yan G F,Li X G,Yuan LJ.Research on biological ac-tivity of nature luteolin[J].Cereals&Oils,2006,3:27-29.
[2]Hu B B(胡碧波),Jiang H D(蒋惠娣),Yang J(杨俊),et al.Determination of luteolin and luteolin-7-β-D-gluco side in chrysanthemum morfolium ramat from dif-ferent collection time by R-P-HPLC[J].Zhejiang Univ(Med Sci),2004,33(1):29-32.
[3]Chen E C,Pannangpetch P,Woodman O L.Relaxationto flavones and flavonols in rat isolated thoracic aorta:mechanism of action and structure-activity relation-ships[J].Cardiovasc Pharm acol,2000,35(2):326-329.
[4]Kang TB,Liang N C.Effect of luteolin on activities ofprotein kinase C and tyrosine protein kinase from HL-60cells[J].Acta Pharmacologica Sinica,1997,18(4):374-376.
[5]Zang H K,Guo X M.Reverse phase high performanceliquid chromatographic determination of luteolin inChrysanthemum[J].Mountain Agriculture and Biology,2002,21(6):424.
[6]LY Q(吕元琦),Wu C H(邬春华),Yuan Z B(袁倬斌).Determination of Apigen in and luteolin in flosbuddlejae by hydroxy propyl-β-cyclodextrin micellarelectrokinetic capillary chromatography[J],Chinese ofAnalytical Chemistry,2005,6,805-807.
[7]Hu L H,Chen Z L.Structure elucidation of a new n-pentyl fructofuranoside in Dendranthen a morifolium(Ramat)tzvel[J].Acta B ot Sin,1997,39(1):85-90.
[8]Brett A M O,Ghica M E.Electrochemical oxidation ofquercetin[J].Electroanalysis,2003,15:1745-1750.
[9]Wu P(吴萍),Chen W(陈伟),Zhang Y F(张亚锋),et al.Electrochemical Behavior and Determination ofCurcumin[J].Electrochemistry,2005(11):346-348.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.