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Abstract

The development and improvement of electrode materials can result in the enhancement of the performances of electrochemical capacitor.In this paper various copper/activated carbon composites were prepared in the presence of different amounts(from 0% to 40%) of copper nitrate from bituminous coal.Then different electrodes were prepared from copper oxide,activated carbon and copper/activated carbon composites,respectively,and were characterized by cyclic voltammetry,alternative current(AC) impedance,charge-discharge at constant current and maintenance of the self-potential.The results showed that the proper amount of copper in copper/activated carbon composites positively influenced the electrochemical performances of electrodes,and the capacitance of copper/activated carbon composites was larger than that of the total of copper oxide and activated carbon.The specific capacitance of composite containing 20% copper reached 67.5 F/g,which is 1.72 times of that of the activated carbon without copper prepared under the same condition.The copper/activated carbons exhibited to better recyclability,higher capacity and lower impedance.However,its maintenance of the self-potential needs to be further investigated and improved.

Keywords

copper nitrate, activated carbon, electrode, electrochemical performance

Publication Date

2008-05-28

Online Available Date

2008-05-28

Revised Date

2008-05-28

Received Date

2008-05-28

References

[1]Jurewicz K,Frackowiak E.Modified carbon materialsfor electrochemical capacitors[J].Molecular PhysicsReports,2000,27:38-45.
[2]Yoon Y S,Cho W L,Lim J H,et al.Solid-state thin-film super capacitor with ruthenium oxide and solid e-lectrolyte thin-film[J].Journal of Power Sources,2001,101(1):126-129.
[3]Dai Gui-ping(戴贵平),Liu Min(刘敏),Wang Mao-zhang(王茂章),et al.Research and development ofcarbon materials for electrochemical capacitorsⅠ.Theelectrochemical capacitor[J].New Carbon Materials,2002,17(1):71-79.
[4]Liu Chen-guang(刘辰光),Liu Min(刘敏),WangMao-zhang(王茂章),et al.Research and developmentof carbon materials for electrochemical capacitorsⅡ.The carbon electrode[J].New Carbon Materials,2002,17(2):64-72.
[5]Wang Fu-rong(王芙蓉),Li Kai-xi(李开喜),LuYong-gen(吕永根),et al.The electrochemical per-formance of phenolic resin-based activated carbon mi-crobeadsⅡ.Preparation and electrochemical perform-ance of activated carbon microbeads as the electrodematerials of EDLC[J].New Carbon Materials,2006,21(3):219-224.
[6]Horvat-Radoevic'V,Kvastek K,Vukovic'M,et al.Elec-trochemical properties of ruthenised electrodes in theoxide layer region[J].Journal of ElectroanalyticalChemistry,2000,482(2):188-201.
[7]Wang Xiao-feng(王晓峰),Wang Da-zhi(王大志),Liang Ji(梁吉),et al.Electrochemical performance ofRuO2/active carbon composite electrodes[J].ActaPhys-Chim Sin,2002,18(8):750-753.
[8]He Yue-de(何月德),Liu Hong-bo(刘洪波),ZhangHong-bo(张红波).The effect of amount of activatingagent on the capacitance characteristics of anthracite-based high surface area activated carbon[J].NewCar-bon Materials,2002,17(4):18-22.
[9]Meng Qing-han(孟庆函),Liu Ling(刘玲),SongHuai-he(宋怀德),et al.Effect of loaded Mn metal onthe specific capacitances of the activated carbon elec-trodes[J].Journal of Functional Materials,2004,35(2):209-211.
[10]SU Yue-feng(苏岳锋),Wu Feng(吴锋),YangZhao-hui(杨朝晖),et al.The application of carbonruthenium composite in alkaline electrochemical ca-pacitors[J].Rare Metal Materials and Engineering,2005,34(11):1734-1737.
[11]Lozano-Castello D,Cazorla-Amoros D,Linares-SolanoA,et al.Influence of pore structure and surfacechemistry on electric double layer capacitance in non-aqueous electrolyte[J].Carbon,2003,41:1765-1775.
[12]Gryglewicz G,Machnikowski J,Lorenc-Grabowska E,et al.Effect of pore size distribution of coal-based ac-tivated carbons on double layer capacitance[J].Elec-trochimica Acta,2005,50:1197-1206.
[13]Meng Qing-han(孟庆函),Liu Ling(刘玲),SongHui-he(宋怀河),et al.Effect of loaded metal onelectrochemical properties of the activated carbon com-posite electrodes[J].Materials Science&Technolo-gy,2005,13(2):119-122.
[14]Meng Qing-han(孟庆函),Liu Ling(刘玲),CaoGao-ping(曹高萍),et al.Study on preparation andproperties of copper chloride/activated carbon elec-trodes for supercapacitor[J].Functional Materials,2005,36(8):1170-1172.
[15]Liu Zhi-chang(刘植昌),Lu Chun-xiang(吕春祥),Ling Li-cheng(凌立成),et al.The preparation of ac-tivated carbon with mesopore by metal-catalyzed car-bon gasification[J].Carbon Techniques,1999.(105):17-20.
[16]Zhang Wen-hui(张文辉),Li Shu-rong(李书荣),Chen Peng(陈鹏),et al.Effect of metal compoundson the preparation of activated carbon from Tai Xi an-thracite[J].Coal Conversion,2000,23(3):82-84.
[17]Zhang Xiang-lan(张香兰),Xu de-ping(徐德平),Cheng Qing-ru(陈靖如).Preparation of activatedcarbon with mesopore by catalyzed method[J].Car-bon,2001,(2):22-25.
[18]Xie Qiang(解强),Zhang Xiang-lan(张香兰),LiLan-ting(李兰廷),et al.Porosity adjustment of acti-vated carbon:theory approaches and practice[J].New Carbon Materials(in Chinese),2005,20(2):183-190.

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