Abstract
The self-assembled film of triethyl phosphate(TEP) formed on the iron surface was found to protect iron from corrosion in 0.5 mol·L-1 H2SO4 efficiently.The inhibition effects were investigated using the electrochemical impedance spectroscopy(EIS).EIS demonstrated that the charge-transfer resistance of the electrode covered with TEP film was greater than that of the naked iron electrodes and the inhibition efficiency of TEP film increased quickly in the initial period and then increased slowly.Quantum chemical calculations provide information about the process of adsorption of molecules on the metal surface at the molecular level.
Keywords
self-assembled films, triethyl Phosphate, electrochemical impedance spectroscopy(EIS)
Publication Date
2008-08-28
Online Available Date
2008-08-28
Revised Date
2008-08-28
Received Date
2008-08-28
Recommended Citation
Wen-juan GUO, Shen-hao CHEN, Wei HE, Xue-hui PANG, Yuan-yuan FENG.
Study of Triethyl Phosphate Self-Assembled Films on Iron for Corrosion Inhibition[J]. Journal of Electrochemistry,
2008
,
14(3): 340-342.
DOI: 10.61558/2993-074X.1918
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol14/iss3/22
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