Abstract
The Ti/SnO2+Sb2O4/PbO2 electrode was prepared.The structure phase and valent state were characterized by means of XRD and XPS.The 2,2-dimethylolpropionic acid was synthesized on the Ti/SnO2+Sb2O4/PbO2 anode by direct electro-oxidation of 2,2-dimethylolpropionaldehyde.The product and crude material were analyzed by HPLC,the effects of the concentration of 2,2-dimethylolpropionaldehyde,pH,potential and reaction temperature were studied.The results showed that the optimum conditions were anode potential 1.8 V,pH=1,reaction temperature 15℃ and 2,2-dimethylolpropionaldehyde concentration 0.10mol/L.Under the optimum conditions,the selectivity of 36%,the current efficiency of 28% and the conversion of 58% were reached.The reported method provides a new route for the synthesis of 2,2-dimethylol propionic acid.
Keywords
Ti/SnO2+Sb2O4/PbO2 electrode, 2, 2-dimethylolpropionaldehyde, 2, 2-dimethylol propionic acid
Publication Date
2009-02-28
Online Available Date
2009-02-28
Revised Date
2009-02-28
Received Date
2009-02-28
Recommended Citation
Hong-Yan SUN, Zhen-Hai LIANG.
Electrosynthesis of 2,2-dimethylolpropionic Acid[J]. Journal of Electrochemistry,
2009
,
15(1): 96-101.
DOI: 10.61558/2993-074X.1963
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol15/iss1/22
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