Abstract
Si-Ag composite materials were prepared by mechanical alloying method. The morphology and composition of SiAg composites were investigated by SEM and XRD. The electrochemical properties of the composites were determined by charge-discharge tests and cyclic voltammetry. The composite composed of Si∶Ag with an atomic ratio of 1∶1 (sample 1#) showed good cyclic stability and charge-discharge reversibility. The reversible capacity of the composite (sample 1#) was remained over 300 mAh·g-1 after 50 cycles. Experimental results showed that controlling the potential range of charge-discharge processes could enhance the cyclic performance of alloy materials.
Keywords
lithium-ion batteries, negative material, mechanical alloying method, Si-based materials
Publication Date
2009-08-28
Online Available Date
2009-08-28
Revised Date
2009-08-28
Received Date
2009-08-28
Recommended Citation
Lian-bang WANG, Xiao-bo DAI, Xin-yan ZHU, Xin-biao MAO, Chun-an MA.
Silicon Silver Composite Materials for Li-ion Batteries[J]. Journal of Electrochemistry,
2009
,
15(3): 275-279.
DOI: 10.61558/2993-074X.1994
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol15/iss3/8
References
[1]Al Hallaj S,Prakash J,Selman J R.Characterization of commercial Li-ion batteries using electrochemical-calori-metric measurements[J].J Power Sources,2000,8(122):186-194.
[2]Yin G P,Zhou D R,Wang Q,et al.Structure and lith-ium intercalation behavior of carbon materials of negative electrodes in lithium-ion batteries[J].Carbon,1999,11(4):31-33.
[3]Shi H,Barkier J,Saidi MY,et al.Structure and lithi-um intercalation properties of synthetic and natural graphite[J].J Electrochem Soc,1996,143(11):3466-3472.
[4]Besenhard J O,Yang J,Winter M.Will advanced lithi-um-alloy anodes have a chance in lithium-ion batteries[J].J Power Sources,1997,68(1):87-90.
[5]Hong L,Huang X J,Chen L Q.The crystal structure e-volution of nano-Si anode caused by lithium Insertion and extraction at room temperature[J].Solid State Ion-ics,2000,135(124):181-191.
[6]Hwang S M,Lee H,Jang S W,et al.Lithium insertion in SiAg powders produced by mechanical alloying[J].Electrochemical and Solid-State Letters,2001,4(7):A97-A100.
[7]Wu X D,Wang Z X,Chen L Q.Ag-enhanced SEI for-mation on Si particles for lithium batteries[J].Electro-chemistry Communications,2003,(5):935-939.
[8]Bourderau S,Borusse I,Schleich D M,et al.Amor-phous silicon as a possible anode material for Li-ion batteries[J].J Power Sources,1999,(81/82):233-236.
[9]Green M,Fielder E,Scrosati B,et al.Structured sili-con anode for lithium battery applications[J].Electro-chemical and Solid-State Letters,2003,6(7):A75-A79.
[10]Morales J,Sanchez L,Martin F,et al.Synthesis characterization,and electrochemical properties of nanocrystalline silver thin films obtained by spray py-rolysis[J].J Electrochem Soc,2004,151(1):A151-A157.
Included in
Engineering Science and Materials Commons, Materials Chemistry Commons, Materials Science and Engineering Commons, Physical Chemistry Commons, Power and Energy Commons