Electrosynthesis of p-aminobenzenearsenic Acid

Authors

Chun-an MA, State Key Laboratory Breeding Base of Green Chemisitry Synthesis Technology,Zhejiang University of Technology,Hangzhou 310032,China;
Qin-an ZHENG, Hangzhou Liqun Environmental Paper Company,Hangzhou 310018,China;
Qiang ZHOU, Hangzhou Liqun Environmental Paper Company,Hangzhou 310018,China;
Ying-hua XU, State Key Laboratory Breeding Base of Green Chemisitry Synthesis Technology,Zhejiang University of Technology,Hangzhou 310032,China;

Corresponding Author

Chun-an MA(science@zjut.edu.cn)

Abstract

The electrochemical reduction of p-nitrophenyl arsonit acid to p-aminobenzenearsenic acid was studied using controlled-current electrolysis.The results showed that the yield of p-aminobenzenearsenic acid was determinated by the following factors:the concentrations of sulphuric acid,the amount of additive,temperature and the concentrations of p-nitrophenyl arsenic acid.The optimum electrolytic conditions were obtained to be is 10% H2SO4,1% NaCl,80 ℃,25 g/350 mL p-nitrophenyl arsenic acid and 10 A·dm-2.The yield of arsanilic acid could be reached 64.7% under the optimum electrolytic conditions.

Keywords

p-nitrophenyl arsonit acid, p-aminobenzenearsenic acid, electrolytic reduction, arsanilic acid

DOI Link

https://doi.org/10.61558/2993-074X.2041

Publication Date

2010-02-28

Online Available Date

2010-02-28

Revised Date

2010-02-28

Received Date

2010-02-28

Recommended Citation

Chun-an MA, Qin-an ZHENG, Qiang ZHOU, Ying-hua XU. Electrosynthesis of p-aminobenzenearsenic Acid[J]. Journal of Electrochemistry, 2010 , 16(1): 70-73.
DOI: 10.61558/2993-074X.2041
Available at: https://jelectrochem.xmu.edu.cn/journal/vol16/iss1/15

References

[1]Guo Xiaozhong(郭效忠),Liu Tianyu(刘天余).The research process of nutrition effect of organic arsenical on livestock and birds[J].Feed Reseach(饲料研究),2000,(10)1:15-17.
[2]Qiu yixiu(邱亦秀).The application of organic arsenical in feed industry[J].Jiangxi Feed(江西饲料),2006,(5):3-4,13.
[3]http://www.chemyq.com/xz/xz11/101312otdff.htm.
[4]Wang zhifeng(王志峰).The use and production of ar-sanilic acid[J].Si Chuan Hua Gong Yu Fu Shi Kong Zhi(四川化工与腐蚀控制),1998,4(1):34-36.
[5]Zhong guoqing(钟国清).Synthesize and application of organic arsenical feed additive[J].Feed Industry(饲料工业),1995,16(7):27-28.
[6]Hermann Hoffmann,Harry E Creen.Production of arsa-nilic acid:US,3763201[P].1973.
[7]Lu Guiqing(卢桂琴),Hong zehu(洪泽湖),Tao Xian-jian(陶贤鉴),et al.The preparation of para-amino-benzenearsenic acid by solvent process[J].Hunan Chemical Industry(湖南化工).1998,28(2):23-24.
[8]Ma Chun-an(马淳安).Introduction to synthetic organ-ic electrochemistry[M].Beijing:Science Press,2002.