Abstract
Nano-sized Au particles were deposited on a nickel foam substrate by a fast spontaneous deposition method using AuCl3 as the source of Au. The effects of AuCl3 concentration and deposition time on the size and distribution of Au particles,and the performance of the obtained Au/Ni electrode as the cathode of Al-H2O2 semi fuel cell were investigated. It was found that after the nickel foam was immersed in a 2 mmol·L-1 AuCl3 solution for 60 s,Au particles with diameters smaller than 100 nm were deposited on its surfaces and cover the surface completely. The Al-H2O2 semi fuel cell with Au/Ni cathode shows a peak power density of 135 mW·cm-2 when operating in 0. 4 mol·L-1 H2O2 solution at room temperature.
Keywords
Au nanoparticles, hydrogen peroxide electroreduction, cathode, metal semi fuel cell
Publication Date
2010-05-28
Online Available Date
2010-05-28
Revised Date
2010-05-28
Received Date
2010-05-28
Recommended Citation
Shu-li CHEN, Bang-an LU, Yao LIU, Gui-ling WANG, Dian-xue CAO.
Nano-sized Au on Nickel Foam as Cathode of Alkaline Al-H_2O_2 Semi Fuel Cell[J]. Journal of Electrochemistry,
2010
,
16(2): Article 20.
DOI: 10.61558/2993-074X.3348
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol16/iss2/20
References
[1]Hasvold,Stakersen N J,Forseth S,et al.Power sources for autonomous underwater vehicles[J].Jour-nal of Power Sources2006,162:935-942.
[2]Sun Li-mei(孙丽美),Cao Dian-xue(曹殿学),Wang Gui-ling(王贵领).Metal semi-fuel cells for underwa-ter power source[J].Chinese Journal of Power Sources(电源技术),2008,32:339-342.
[3]Hasvold,Johansen K H,Mollestad O,et al.The alka-line aluminium/hydrogen peroxide power source in the Hugin II unmanned underwater vehicle[J].Journal of Power Sources1999,80:254-260.
[4]Gu L,Luo N,Miley G H.Cathode electrocatalyst selec-tion and deposition for a direct borohydride/hydrogen peroxide fuel cell[J].Journal of Power Sources2007,173:77-85.
[5]Miley G H,Luo N,Mather J,et al.Direct NaBH4/H2O2fuel cells[J].Journal of Power Sources,2007,165:509-516.
[6]Patrissi C J,Bessette R R,Kim Y K,et al.Fabrication and rate performance of a microfiber cathode in a Mg-H2O2flowing electrolyte semi-fuel cell[J].Journal of the Electrochemical Society,2008,155:B558-B562.
[7]Bessette R R,Cichon J M,Dischert D W,et al.A study of cathode catalysis for the aluminium/hydrogen perox-ide semi-fuel cell[J].Journal of Power Sources,1999,80:248-253.
[8]Medeiros M G,Bessette R R,Deschenes C M,et al.Magnesium-solution phase catholyte semi-fuel cell for undersea vehicles[J].Journal of Power Sources,2004,136:226-231.
[9]Yang W,Yang S,Sun W,et al.Nanostructured silver catalyzed nickel foam cathode for an aluminum-hydro-gen peroxide fuel cell[J].Journal of Power Sources,2006,160:1420-1424.
[10]Yang W,Yang S,Sun W,et al.Nanostructured palla-dium-silver coated nickel foam cathode for magnesium-hydrogen peroxide fuel cells[J].Electrochimica Acta,2006,52:9-14.
[11]Cao D,Chen D,Lan J,et al.An alkaline direct Na-BH4-H2O2fuel cell with high power density[J].Jour-nal of Power Sources,2009,190:346-350.
[12]Cao D,Sun L,Wang G,et al.Kinetics of hydrogen per-oxide electroreduction on Pd nanoparticles in acidic medium[J].Journal of Electroanalytical Chemistry,2008,621:31-37.
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