Research on Electrochemical Performance of Lithium-Ion Battery Cathode Material LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2 in Aqueous LiNO_3 Solution

Authors

Jun ZHENG, State Key Lab of Physical Chemistry of Solid Surfaces,Department of Chemistry, College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,Fujian,China;
Xin JIA, State Key Lab of Physical Chemistry of Solid Surfaces,Department of Chemistry, College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,Fujian,China;
Chong WANG, State Key Lab of Physical Chemistry of Solid Surfaces,Department of Chemistry, College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,Fujian,China;
Ming-sen ZHENG, State Key Lab of Physical Chemistry of Solid Surfaces,Department of Chemistry, College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,Fujian,China;
Quan-feng DONG, State Key Lab of Physical Chemistry of Solid Surfaces,Department of Chemistry, College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,Fujian,China;

Abstract

The cathode material of LiNi1/3Co1/3Mn1/3O2 synthesized by sol-gel method shows excellent high rate performance,and high output power density during discharge process. A well-ordered layered α-NaFeO2 structure was confirmed by XRD and a primary particle size of about 500 nm was indicated by SEM. Galvanostatic charge-discharge test indicates that LiNi1/3Co1/3Mn1/3O2 in 2 mol·L-1 LiNO3 aqueous solution with pH 12 reached a ca-pacity of 147 mAh/g while charged and discharged at 2C. The capacities were 64、33、16 mAh/g with 80C ( 14. 4 A/g) 、150C( 27 A/g) and 220C ( 39. 6 A/g) charge/discharge rates,while the power densities of the battery were 2574 W/kg、3925 W/kg、4967 W/kg,respectively. It retained 90. 9% of the initial capacity after 1000 cycles at 80 C.

Keywords

aqueous lithium-ion battery, LiNi1/3Co1/3Mn1/3O2, cathode material, sol-gel method

DOI Link

https://doi.org/10.61558/2993-074X.3337

Publication Date

2010-05-28

Online Available Date

2010-05-28

Revised Date

2010-05-28

Received Date

2010-05-28

Recommended Citation

Jun ZHENG, Xin JIA, Chong WANG, Ming-sen ZHENG, Quan-feng DONG. Research on Electrochemical Performance of Lithium-Ion Battery Cathode Material LiNi_(1/3)Co_(1/3)Mn_(1/3)O_2 in Aqueous LiNO_3 Solution[J]. Journal of Electrochemistry, 2010 , 16(2): Article 9.
DOI: 10.61558/2993-074X.3337
Available at: https://jelectrochem.xmu.edu.cn/journal/vol16/iss2/9