Research on Electrochemical Performance of Lithium-Ion Battery Cathode Material LiNi_(1/3)Co_(1/3)Mn_(1/3)O₂ in Aqueous LiNO₃ Solution

Authors

• Jun ZHENG, State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005,Fujian,China;
• Xin JIA, State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005,Fujian,China;
• Chong WANG, State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005,Fujian,China;
• Ming-sen ZHENG, State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005,Fujian,China;
• Quan-feng DONG, State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005,Fujian,China;Follow

Corresponding Author

Quan-feng DONG(qfdong@xmu.edu.cn)

Abstract

The cathode material of LiNi_1/3Co_1/3Mn_1/3O₂ synthesized by sol-gel method shows excellent high rate performance, and high output power density during discharge process. A well-ordered layered α-NaFeO₂ structure was confirmed by XRD and a primary particle size of about 500 nm was indicated by SEM. Galvanostatic charge-discharge test indicates that LiNi_1/3Co_1/3Mn_1/3O₂ in 2 mol·L^-1 LiNO₃ aqueous solution with pH 12 reached a ca-pacity of 147 mAh/g while charged and discharged at 2C. The capacities were 64, 33, 16 mAh/g with 80C (14.4 A/g), 150C (27 A/g) and 220C (39.6 A/g) charge/discharge rates,while the power densities of the battery were 2574 W/kg, 3925 W/kg, 4967 W/kg, respectively. It retained 90. 9% of the initial capacity after 1000 cycles at 80 C.

Keywords

aqueous lithium-ion battery, LiNi1/3Co1/3Mn1/3O2, cathode material, sol-gel method

DOI Link

https://doi.org/10.61558/2993-074X.3337

Publication Date

2010-05-28

Online Available Date

2010-05-28

Revised Date

2009-11-20

Received Date

2009-10-21

Recommended Citation

Jun ZHENG, Xin JIA, Chong WANG, Ming-sen ZHENG, Quan-feng DONG. Research on Electrochemical Performance of Lithium-Ion Battery Cathode Material LiNi_(1/3)Co_(1/3)Mn_(1/3)O₂ in Aqueous LiNO₃ Solution[J]. Journal of Electrochemistry, 2010, 16(2): 151-155.
DOI: 10.61558/2993-074X.3337
Available at: https://jelectrochem.xmu.edu.cn/journal/vol16/iss2/9