Abstract
The PbO2 anodes were prepared on platinum from fluoroborate media and its doped solutions by electrodeposition technique.Elecchemical and pysicochemical properties of these PbO2 films were studied by cyclic voltammetry methods,XRD and SEM.The results showed that the presence of BF4-increased PbO2 electrodeposition rate;the prepared lead dioxide consisted of β-PbO2;the preferential orientation of crystals and surface morphology were affected a lot by doping F-and Fe3+.The FB/F-Fe-PbO2 electrode exhibited regular-shaped layers with compact morphology.Furthermore,increasing current density also change the preferential orientation of PbO2 crystals.
Keywords
PbO2, electrodeposition, fluoroborate
Publication Date
2010-11-28
Online Available Date
2010-11-28
Revised Date
2010-11-28
Received Date
2010-11-28
Recommended Citation
Chun-mei KONG, Yong-ming TANG, Wen-zhong YANG, Xiao-yuan YANG.
Electrodeposition of Lead Dioxide from Dluoroborate Solutions[J]. Journal of Electrochemistry,
2010
,
16(4): 446-449.
DOI: 10.61558/2993-074X.2069
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol16/iss4/15
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