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Abstract

The low temperature performance of electrolytes containing FEC including FEC+EMC,EC and PC,as well as the compatibility of electrolytes with LiFePO4 anode and with MCMB cathode were investigated.The electrolyte exhibits a high value of ionic conductivity at low temperature.The stability of cathode was enhanced by the formation of SEI film at 1.6 V as a result of FEC reaction.The infrared spectra showed that FEC can suppress decomposition of other solvents during SEI formation,and lower the resistance of SEI on MCMB cathode.The electrochemistry test indicates that Li-ion batteries with FEC electrolyte display high capacity at low temperature and better rate performance.

Keywords

Li-ion battery, low-temperature performance, LiFePO4, FEC

Publication Date

2011-02-28

Online Available Date

2011-02-28

Revised Date

2011-02-28

Received Date

2011-02-28

References

[1]Xu Jie(许杰),Yao Wan-hao(姚万浩),Yao Yi-wen(姚宜稳),et al.Effect of fluoroethylene carbonate addi-tive on the performance of lithium ion battery[J].ActaPhys-Chim Sin(物理化学学报),2009,25(2):201-206.


[2]Profatilova I A,Kim S S,Choi N S.Enhanced thermalproperties of the solid electrolyte interphase formed ongraphite in an electrolyte with fluoroethylene carbonate[J].Electrochimica Acta,2009,54(19):4445-4450.


[3]Ryou M H,Han G B,Lee Y M,et al.Effect of fluoroeth-ylene carbonate on high temperature capacity retentionof LiMn2O4/graphite Li-ion cells[J].ElectrochimicaActa,2010,55(6):2073-2077.


[4]Aurbach D,Gamolsky K,Markovsky B,et al.On the useof vinylene carbonate(VC)as an additive to electrolytesolutions for Li-ion batteries[J].Electrochim Acta,2002,47(9):1423-1439.

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