Study on Direct Electro-Oxidation of Anisaldehyde

Authors

Lin-lin Wu, College of Chemical Engineering and Materials Science of Zhejiang University of Technology, State Key Laboratory Breeding Base of Green Chemistry, Zhejiang University of Technology, Hangzhou 310032, Zhejiang,China;
Ying-hong Zhu, College of Chemical Engineering and Materials Science of Zhejiang University of Technology, State Key Laboratory Breeding Base of Green Chemistry, Zhejiang University of Technology, Hangzhou 310032, Zhejiang,China;
Shan-shan Li, College of Chemical Engineering and Materials Science of Zhejiang University of Technology, State Key Laboratory Breeding Base of Green Chemistry, Zhejiang University of Technology, Hangzhou 310032, Zhejiang,China;
Hong-yan Zeng, College of Chemical Engineering and Materials Science of Zhejiang University of Technology, State Key Laboratory Breeding Base of Green Chemistry, Zhejiang University of Technology, Hangzhou 310032, Zhejiang,China;
Chun-an Ma, College of Chemical Engineering and Materials Science of Zhejiang University of Technology, State Key Laboratory Breeding Base of Green Chemistry, Zhejiang University of Technology, Hangzhou 310032, Zhejiang,China;Follow

Corresponding Author

Chun-an Ma(science@zjut.edu.cn)

Abstract

University of Technology, Hangzhou 310032, Zhejiang,China)
Abstract: The oxidation of anisole on Pt electrode was investigated by cyclic voltammery and constant potential electrolysis. The influence of scan rates, substrate concentration, supporting electrolytes and solvent were considered . The results show that the electro-oxidation process of anisole was irreversible. In this research the sulfuric acid was the best supporting electrolytes and acetone was the best solvent, and the process was controlled by diffusion . The product of constant potential electrolysis was charactered by GC-MS .The results show that the main products was anisaldehyde, and the selectivity was up to 66.5% when using acetone as solvent.

Graphical Abstract

Keywords

anisole, electro-oxidation, anisaldehyde

DOI Link

https://doi.org/10.61558/2993-074X.2091

Publication Date

2011-05-28

Online Available Date

2011-05-06

Revised Date

2010-12-30

Received Date

2010-11-04

Recommended Citation

Lin-lin Wu, Ying-hong Zhu, Shan-shan Li, Hong-yan Zeng, Chun-an Ma. Study on Direct Electro-Oxidation of Anisaldehyde[J]. Journal of Electrochemistry, 2011 , 17(2): 227-230.
DOI: 10.61558/2993-074X.2091
Available at: https://jelectrochem.xmu.edu.cn/journal/vol17/iss2/11