Abstract
Electrochemical behaviors of Zn in 3mol•L-1 KOH solution containing the single additive( Pb(NO3)2 , SDBS )the mixed additives( Pb(NO3)2+SDBS ) were investigated. The results showed that all the additives can supress the corrosion of zinc in 3mol•L-1 KOH solution. And the inhibition effeciency of the mixed additives is higher than that of any single additive.
Graphical Abstract
Keywords
additives, zinc, inhibition, electrochemical behavior
Publication Date
2011-05-28
Online Available Date
2011-05-06
Revised Date
2010-11-20
Received Date
2010-08-11
Recommended Citation
Shu-na HONG, Hai-bin LIN, Zuo-jian SU, He-bing ZHOU, Man LIANG, Wei-shan LI.
Effects of Additives on the Electrochemical Behaviors of Zn Electrode in Alkaline Solutions[J]. Journal of Electrochemistry,
2011
,
17(2): Article 13.
DOI: 10.61558/2993-074X.2828
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol17/iss2/13
References
[1] Chang Woo Lee, K. Sathiyanarayanan, Seung Wook Eom, et al. Novel alloys to improve the electrochemical behavior of zinc anodes for zinc/air battery[J]. Journal of Power Sources, 2006, 160(2): 1436-1453.
[2] Barbara Szcze´sniak, Maria Cyrankowska, Alfred Nowacki. Corrosion kinetics of battery zinc alloys in electrolyte solutions[J]. Journal of Power Sources, 1998, 75(1): 130138.
[3] Li Feng(李峰), Liu Hai-jing(刘海晶), Wang Yong-gang(王永刚), et al. Comparison of catalytic performance of Mn3O4-loaded two-dimensional and tree-dimensional msoporous carbon mterials in Znc-air bttery [J]. Chemical Journal of Chinese Universities(in Chinese), 2007, 28(11):2133-2137.
[4] Cheng Yan(程岩), Yu Ming(于明), Yan Man-ming(严曼明), et al. Electrochemical behavior and reduction mechanism of high valence silver oxide Ag3o4 in alkaline solution [J]. Electrochemistry(in Chinese), 2006(5), 12(2):134-139.
[5] Wang Sheng-wei(王升威), Yang Zhan-hong(杨占红), Zeng Li-hui(曾利辉), et al. Self-discharge performance of sealed Ni-Zn battery[J]. Chinese Journal of Power Sources(in Chinese), 2008, 32(4): 58-60.
[6] Wang Sheng-bing(王胜兵), Guo Long(郭龙), Liu Bing(刘兵), et al. Research on improvement of shelf-performance for mercury-free alkaline Zn-MnO2 batteries [J]. Chinese Battery Industry, 2008, 13(1): 46-48.
[7] Kunitusugu Aramaki. Effects of organic inhibitors on corrosion of zinc in an aerated 0.5M NaCl solution[J]. Corrosion Science, 2001, 43(10):1985~2000.
[8] Wang Jian-ming(王建明), Cao Chu-nan(曹楚南), Lin Hai-chao(林海潮). Electrochemical corrosion behavior of zinc in koh solutions[J]. Journal of Chinese Society for Corrosion and Protection(in Chinese), 1996, 16(4): 263~268.
[9] Yan Li-jing(闫丽静), He Yu-fan(何毓璠), Lin Hai-chao(林海潮), et al. Study on the inhibition effect of polymer film of propargyl alcohol in Fe/H2SO4 and Fe/ H2SO4 + H2S systems [J]. Acta Physico-chimica Sinica(in Chinese), 1999, 15(8): 726~734.
[10] Kunitusugu Aramaki. Effects of organic inhibitors on corrosion of zinc in an aerated 0.5M NaCl solution[J]. Corrosion Science, 2001, 43(10):1985~2000.
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