Abstract
By using defects on the surface of CMK-3 served as nucleation center, Co0.25Ni0.75 oxide/C composite was successfully prepared through a simple chemical co-precipitation method. Characterization was carried by using X-ray diffraction, BET and scanning electron microscopy. Results showed that a perfect mesoporous network of interconnected nanoflakes was obtained for Co0.25Ni0.75 oxide/C composite and, this material has a less crystallization, interconnected nanoflakes network structure and a narrow mesoporous distribution at about 3~4 nm. The highly dispersed and loosely packed Co0.25Ni0.75 oxide/C composite possessed good electrochemical accessibility and fast diffusion rate of OH-. Cyclic voltammetry, charge–discharge curves suggested that the as-prepared Co0.25Ni0.75 oxide(92%) /C electrode is highly electrochemical activated and an admirable specific capacitance of as high as 1781 F/g could be obtained at current density of 5mA/cm2.
Graphical Abstract
Keywords
supercapacitor;, cobalt-nickel oxide;, interconnected nanoflakes network
Publication Date
2011-05-28
Online Available Date
2011-05-05
Revised Date
2011-03-15
Received Date
2011-01-07
Recommended Citation
Zhen-Sheng YANG, Ling-Bin KONG, Li DENG, Yong-Chun LUO, Long KANG.
Electrochemical Capacitive Performance of Mesoporous Carbon Based Co-Ni Oxides[J]. Journal of Electrochemistry,
2011
,
17(2): Article 19.
DOI: 10.61558/2993-074X.2834
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol17/iss2/19
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