Abstract
The electrochemical behavior and possible reaction mechanism in Fe(Ⅲ)-oxalate-calcium gluconate system were studied by cyclic voltammetry. The results showed that Fe(Ⅱ)-gluconate was the final reductant. The reduction time, the working voltage and the cathode area influenced the current efficiency. The high current efficiency of 89% for the indirect electrochemical reduction of Vat Scarlet R could be achieved with reduction time of 10 min, working voltage of 4 V and cathode area of 40 cm2 in Fe(Ⅲ)-oxalate-calcium gluconate system.
Graphical Abstract
Keywords
cyclic voltammetry (CV), current efficiency;working voltage, cathode area, Fe(Ⅲ)-oxalate-calcium gluconate system;cotton dyeing
Publication Date
2011-11-28
Online Available Date
2011-09-29
Revised Date
2011-08-17
Received Date
2011-07-12
Recommended Citation
Qing-Zhi WANG, Wei WANG.
Indirect Electrochemical Reduction and Cotton Dyeing Process in Fe(Ⅲ)-Oxalate-Calcium Gluconate System[J]. Journal of Electrochemistry,
2011
,
17(4): Article 16.
DOI: 10.61558/2993-074X.2869
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol17/iss4/16
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