Abstract
The mesh-like structure of NiO electrode was obtained by first preparing the precursors via hydrothermal process using nickel sulfate and carbamide as reactants, sodium hexametaphosphate as a surfactant, and followed by calcination of the precursors at 400 ℃. The structure, morphology and capacitance characteristics of NiO electrode were characterized by XRD, SEM and constant current charge-discharge testing techniques. The effects of hydrothermal temperatures on the electrochemical properties of NiO electrode were investigated. The results showed that the better property of nickel oxide was obtained when the mole ratio of nickel to urea was 1:4 and the hydrothermal temperature was 140℃. The specific discharge capacitance of the NiO electrode was up to 939 F?g-1 at 20 mA?cm-2.
Graphical Abstract
Keywords
NiO, mesh-like structure, capacitance characteristics
Publication Date
2011-11-28
Online Available Date
2011-09-22
Revised Date
2011-08-31
Received Date
2011-08-05
Recommended Citation
Hui XU, Zhen-Jun PENG, Dong-Hong GUO, Jun-Ling LI.
Preparation and Capacitance Characteristics of Nickel Oxide Electrode with Mesh-Like Structure[J]. Journal of Electrochemistry,
2011
,
17(4): Article 17.
DOI: 10.61558/2993-074X.2870
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol17/iss4/17
References
[1] Sonavane A C, Patil P S, Patil R S, et al. Efficient electrochromic nickel oxide thin films by electrodeposition[J]. Journal of Alloys and Compounds,2010,489(2):667-673.
[2] Xing W, Li F, Yan Z F, Synthesis and electrochemical properties of mesoporous nickel oxide [J]. Journal of Power Sources, 2004,134(2):324-330.
[3] Wang Y P, Zhu W J, Lu D L. Preparation of NiO nanoparticles and their catalytic activity in the thermal decomposition of ammonium perchlorate[J]. Thermochim Acta, 2005,437(1/2):106-109.
[4] Ghosh M, Biswas K, Sundaresan A. MnO and NiO nanoparticles: synthesis and magnetic properties[J]. J Mater Chem , 2006,16(1):106-111.
[5] Sietama J R A, Meeldijk J D, Breejen J P D J. The preparation of supported NiO and Co3O4 nanoparticles by the nitric oxide controlled thermal decomposition of nitrates[J]. Chem Int Ed, 2007,46(24):4547-4549.
[6] Wu M S, Hsieh H H. Nickel oxide/hydroxide nanoplates synthesized by chemical precipition for electrochemical capacitiors[J]. Electrochimica Acta,2008,53(8),3427-3435
[7] Xu K C, Hong Q K, Liu S. A novel wet chemical route to NiO nanowires[J]. J Cryst Growth, 2003,255(3-4):308-312.
[8] Deng J J, Deng J C, Liu Z L, Influence of addition of cobalt oxide on microstructure and electrochemical capacitive performance of nickel oxide[J]. J Solid State Electrochem, 2009,13(9):1387-1394.
[9] Zheng M B, Cao J M, Chen Y P. Facile fabrication of nickel oxide hollow spheres and amorphous carbon/nickel nanoparticles composites using colloidal carbonaceous microspheres as template[J]. Chem Lett ,2005,34(8):1174-1175.
[10] Wu L L, Wu Y S, Wei H Y. Synthesis and characteristics of NiO nanowire by a solution method[J]. Mater Lett , 2004,58(21):2700-2703.
[11] Zhao Sheng-li (赵胜利),Wen Jiu-ba(文九巴),Wang Hong-kang (王红康),et al. Preparation and electrochemical properties of nanocrystalline NiO[J]. Chinese Journal of Materials Research(材料研究学报),2008,22(4):415-419.
[12] Liu X M, Zhang X G, Fu S Y. Preparation of urchinlike NiO nanostructures and their electrochemical capacitive behaciors[J]. Materials Research Bulletin,2006,41(3):620-627.
Included in
Catalysis and Reaction Engineering Commons, Engineering Science and Materials Commons, Materials Chemistry Commons, Materials Science and Engineering Commons, Physical Chemistry Commons, Power and Energy Commons