Abstract
Silver was deposited on the surface of polyaniline coated polyamide fabrics by electroless plating without using conventional palladium chloride solution as activator．Effects of electroless plating conditions such as the concentrations of silver nitrate, reducing agent glucose, complexing agent ammonium hydroxide, sodium hydroxide in the bath, as well as the depositing time and bath temperature on the rate of metal deposition and the square resistance were studied. Optimum electroless plating conditions were: 30℃, 50 min, with silver nitrate 12 g/L, ammonium hydroxide 100 ml/L, glucose 2.8 g/L, sodium hydroxide 8 g/L. Meanwhile, effects of the intermediate polyaniline layer on the metal crystallite size, texture and corrosion resistance of composite conducting fabrics were discussed. The results showed that the intermediate polyaniline layer between polyamide fabric and silver could effectively improve the conductance, corrosion resistance and laundry resistance of composite conducting fabrics.
Graphical Abstract
Keywords
Pd-free activation, electroless plating, sliver, polyaniline, conducting fabric
Publication Date
2011-11-28
Online Available Date
2011-08-10
Revised Date
2011-07-28
Received Date
2011-07-05
Recommended Citation
Yun MENG, Ya ping ZHAO, Zai sheng CAI.
Electroless Plating Silver without Pd Activation on Polyamide Fabrics and Its Properties[J]. Journal of Electrochemistry,
2011
,
17(4): Article 5.
DOI: 10.61558/2993-074X.2858
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol17/iss4/5
References
[1] Snouqiang Jiang, Edward Newton, Chun-Wah Marcus Yuen, et al. Application of chemical silver plating on polyester and cotton blended fabric[J]. Textile Research Journal, 2007, 77(2): 85–91.
[2] Padilla A P, Rodríguez J A, Saitúa H A. Synthesis and water ultrafiltration properties of silver membrane supported on porous ceramics[J]. Desalination, 1997, 114: 203-208.
[3] Jiao H J(焦红娟), Guo H X(郭红霞), Li Y Q(李永卿), et al. Preparation and properties of conductive silver-coated PET fibers[J]. Journal of East China University of Science and Technology (华东理工大学学报). 2006, 32(2): 173-176.
[4] Jiang X X(姜晓霞), Shen W(沈伟). Electroless plating theory and its practice(化学镀理论及实践)[M]. Beijing: Defense Industry Press, 2000: 237.
[5] Gitanjali M, Mausumi G, Kumar S T, et a1. Au nanoparticles and polyaniline coated resin beads for simultaneous catalytic oxidation of glucose andcolorimetric detection of the product[J]. Langmuir, 2005, 21(5): 1663-1667.
[6] Tseng R J, Huang J X, Ouyang J Y, et a1. Polyaniline nanofiber/gold nanoparticle nonvolatile memory[J]. Nano Letters, 2005, 5(6): 1077-1080.
[7] Li L, Yan G P, Wu J Y, et a1. Preparation of polyaniline-metal composite nanospheres by in situ microemulsion polymerization[J]. Journal of Colloid and Interface Science, 2008, 326(1): 72-75.
[8] Dallas P, Niarchos D, Vrbanic D, et a1. Interfacial polymerization of pyrrole and in-situ synthesis of polypyrrole/silver nanocomposites[J]. Polymer, 2007, 48(7): 2007-2013.
[9] Ma Z H, Tan K L, Kang E T. Electroless plating of palladium and copper on polyaniline fimls[J]. Synthetic Metals, 2000, 114(10): 17-25.
[10] Nowoo Park, Il Won Kim, Jooyong Kim. Copper metallization of poly(ethylene terephthalate) fabrics via intermediate polyaniline layers[J]. Fibers and Polymer, 2009, 10(3): 310-314.
[11] Zhou Z Y(周兆懿), Zhao Y P(赵亚萍), Cai Z S(蔡再生), et al. Preparation and characterization of inorganic acids doped polyaniline on PET fibers[J]. Chemical Industry and Engineering Progress(化工进展), 2010, 29(5): 909-913.
[12] Zhou Z Y(周兆懿), Zhao Y P(赵亚萍), Cai Z S(蔡再生). Preparation of polyaniline/polyester conducting composite fabric with in-situ polymerization[J]. Dyeing and Finishing(印染), 2009, 35(5): 1-5.
[13] Zhao Y P(赵亚萍), Zhou Z Y(周兆懿), Cai Z S(蔡再生), et al. Effect of oxidative conditions on properties of polyaniline/polyester conducting fabrics[J]. Dyeing and Finishing(印染), 2010, 36(4): 1-6.
[14] Zhou Z Y(周兆懿), Cai Z S(蔡再生), Zhao Y P(赵亚萍), et al. Thermal stability of hydrochloride doped polyaniline on PET fibers [J]. New Chemical Materials(化工新型材料), 2010, 38(11): 75-77.
[15] Zhao Y P, Zhou Z Y, Fu X L, et al. Thermodynamics study of monomer adsorption process for fabrication of conductive textiles[M]. Proceedings of the Second International Conference on Advanced Textile Materials &Manufacturing Technology, Hangzhou: Zhejiang University Press, 2010, 20-24.
[16] Zhao Y P, Cai Z S, Zhou Z Y, et al. Adsorption behavior of monomers and formation of conducting polymers on polyester fibers[J]. Journal of Applied Polymer Science. 2011, 119(2): 662–669.
[17] Fu X L(符晓兰), Zhao Y P(赵亚萍), Cai Z S(蔡再生). Preparation of polyaniline/metal composite conductive fabric by electroless plating[J]. Dyeing and Finishing(印染), 2010(18): 1-4.
[18] Wang Z(王政), Zhao J X(赵炯心). The study of chemical silver plating on polyurethane fiber[J]. Synthetic Technology and Application (合成技术及应用), 2006, 21 (3): 35-39.
[19] Zhang H (张辉), Zhan J C(詹建朝), Shen L P(沈兰萍). Electroless silver plating of PET fabric enhanced by ultrasonic wave[J]. Surface Technology(表面技术), 2006, 35(5): 37-39.
[20] Zhang B W(张邦维), Hu W Y(胡望宇), Wang L L(王玲玲), et al. Effects of plating process parameters on electroless deposition rate[J]. Electroplating and Pollution Control(电镀与环保), 1999, 19(5): 15-22.
[21] Miroslava Trchová, Jaroslav Stejskal. The reduction of silver nitrate to metallic silver inside polyaniline nanotubes and on oligoaniline microspheres[J]. Synthetic Metals, 2010,160: 1479–1486.
[22] Jiang S X(姜绶祥), Guo R H(郭荣辉), Zheng G H(郑光洪). Crystal structure and properties of electroless silver plating on polyester fabric[J]. Electroplating and Finishing (电镀与涂饰), 2009, 28(7): 22-24.
[23] Klug H P, Alexander L E. X-ray diffraction procedures for polycrystalline and amorphus materials[M]. New York: John Wiley& Sons, 1974:196-200.
[24] Dai H B(戴洪斌). Study of the texture of electrodeposited Fe-Ni alloy[J]. Electroplating and Finishing (电镀与涂饰), 1994, 14(6): 5-7.
[25] Xu S K(许书楷), Yang F Z(杨防祖), Zhou S M(周绍民). Effect of deposition conditions on the texture of zinc deposits[J]. Electrochemistry (电化学), 1995, 1 (4): 408-413.
[26] Su Y Q(苏永其), Liu R(刘瑞), Yao J Y(姚锦元), et al. Corrosion mechanism of nanocrystalline zinc coating on steel sheet used for automobile in NaCl solution[J]. Electroplating and Finishing(电镀与涂饰), 2011, 30(1): 10-13.
