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Corresponding Author

Hai-Chang ZHANG(hchzhang@126.com)

Abstract

In this paper, the effects of overcharge, charge-discharge C rate and pore size on cycle lifetime of 4.5’ electrochemical impregnated nickel electrode were investigated. In the case of the electrode was overcharged to 170% of nominal capacity, the initial capacity of the electrode could be maintained 2.7 Ah up to 150 cycles without deterioration and a discharge capacity of 1.7 Ah (remaining 63% of 2.7 Ah ) could be delivered after 300 cycles. Without overcharge, more than 300 charge-discharge cycles could be realized without loss of capacity and a discharge capacity of electrode could be maintained about 76% of initial capacity even after 1000 cycles. The experimental results also showed that without overcharge the increase in pore size and activation with small current could improve the electrode cycle capability.

Graphical Abstract

Publication Date

2012-02-28

Online Available Date

2011-11-01

Revised Date

2011-09-21

Received Date

2011-08-10

References

[1] Lawrence H. Thaller ,Albert H. Zimmerman. Overview of the Design, Development, and Application of Nickel-Hydrogen Batteries[M]. California: NASA Center for AeroSpace Information, 2003:12-13

[2] Prolong V, Chabre Y, Delahaye-Vidal A, et al. Study of the contribution of cobalt additive to the behavior of the nickel oxy-hydroxide electrode by potentiodynamic techniques[J].Solid State Ionics,2002,147:73-84

[3] Fun X Z, Xu Q C, Hu R Z, et al. β-CoOOH coated spherical β-NiOOH as the positive electrode material for alkaline Zn-NiOOH battery[J].J Power sources,2007,164:916-920

[4] Yuan A B, Cheng S A, Zhang J Q, et al. Effect of metallic cobalt addition on the performance of pasted nickel electrodes[J].J Power sources,1999,77:178-182

[5] Zhang Y S, Cao X Y, Yuan H T, et al. Oxygen evolutio reaction on Ni hydroxide film electrode containing various content of Co[J].International journal of hydrogen energy,1999,24:529-536

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