Abstract
The Ag nanoparticles were prepared in aqueous solutions through a chemical reduction method and transferred from water phase to toluene phase with the protection of 1-dodecanethiol (DDT). The polished iron electrode was immersed in the DDT-protected metal nanoparticles toluene solutions to form DDT/Ag nanoparticles self-assembled mixed films. Electrochemical methods such as electrochemical impedance spectroscopy and polarization curve measurement were used to study the inhibition properties of the self-assembled films in the 0.5 mol?L-1 H2SO4 solution. The appearance of elements such as S and Ag from the XPS data identified the presences of DDT and Ag nanoparticles.
Graphical Abstract
Keywords
Ag nanoparticles, iron, self-assembled, inhibitor
Publication Date
2012-02-28
Online Available Date
2011-11-03
Revised Date
2011-10-31
Received Date
2011-04-18
Recommended Citation
ZHANG Zhe, JIA Ming-Zi, RUAN Le.
Ag Nanoparticles Self-assembled Films on Iron Surface and Their Inhibition Properties[J]. Journal of Electrochemistry,
2012
,
18(1): Article 15.
DOI: 10.61558/2993-074X.2886
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol18/iss1/15
Included in
Materials Chemistry Commons, Nanoscience and Nanotechnology Commons, Physical Chemistry Commons