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Corresponding Author

Guang-Hui HU(qhxy123@126.com)

Abstract

The Ni-P-TiO2 composite coating electrodes with different contents of TiO2 particulates were prepared by electroless plating technique from Ni-P plating bath containing TiO2 powders on brass. Cyclic voltammetry, linear sweep voltammetry (LSV), chronoamperometry and electrochemical impedance spectroscopy (EIS) were used to test the electrochemical performance of Ni-P-TiO2/Cu electrodes. It was indicated that the Ni-P-TiO2/Cu electrodes exhibited very strong electrocatalytic activity toward the oxidation of ethanol in alkaline medium at ambient temperature. The electrocatalytic activity of ethanol oxidation on the Ni-P-TiO2 electrodes depended on the amounts of TiO2 in the coatings. The excellent capacity on electrocatalytic oxidation of ethanol was obtained with the electrodes prepared in Ni-P plating bath containing 5 g?L-1 TiO2.

Graphical Abstract

Keywords

electroless plating, Ni-P-TiO2 composite coating, ethanol;electrocatalytic oxidation

Publication Date

2012-04-28

Online Available Date

2011-11-01

Revised Date

2011-10-09

Received Date

2011-09-23

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