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Corresponding Author

Xiang-Ming HE(hexm@tsinghua.edu.cn)

Abstract

In this paper, an impedance model is developed for simulating the discharge curve of LiFePO4 cathode material. The voltage drop is divided into three parts: the Ohm voltage drop, the charge transfer voltage drop and the diffusion voltage drop. A theoretical expression has been derived to predict the discharge curves at various discharge rates. The parameters of the equation have been obtained by fitting the results of EIS measurement, and a good agreement between the fitting and the experimental data has been found at all discharge rates.

Graphical Abstract

Keywords

LiFePO4, impedance model, fitting

Publication Date

2012-08-28

Online Available Date

2012-02-01

Revised Date

2012-01-19

Received Date

2011-11-24

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