Abstract
The anode materials of Sn-Co-M-C (M = Zn, Fe) composites were prepared by carbothermal reduction method from metal oxides and sucrose in N2 atmosphere. Their structural and electrochemical properties were studied by XRD, SEM and charge-discharge test. Among them, the Sn-Co-Zn-C composite showed higher specific capacity and good cycle performance. The initial specific discharge capacity of 571 mAh.g-1 could be obtained, while 369 mAh.g-1 was still kept after 45 cycles.
Graphical Abstract
Keywords
carbothermal reduction method, lithium-ion battery, cathode material, Sn-based alloy
Publication Date
2012-08-28
Online Available Date
2012-02-21
Revised Date
2012-02-16
Received Date
2011-11-24
Recommended Citation
Guo-Qing FANG, Wei-Wei LIU, Shi-Ci HE, Qian ZHANG, Jun-Wei ZHENG, De-Cheng LI.
Preparation and Performance of Sn-Co-M-C(M = Zn, Fe)Composites as an Anode Material[J]. Journal of Electrochemistry,
2012
,
18(4): Article 9.
DOI: 10.61558/2993-074X.2926
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol18/iss4/9
References
[1] Winter M, Besenhard J. Electrochemical lithiation of tin and tin-based intermetallics and composites [J]. Electrochimica Acta, 1999, 45 (1/2): 31-50.
[2] Benedek R, Thackeray M. Lithium reactions with intermetallic-compound electrodes [J]. Journal of Power Sources, 2002, 110(2): 406-411.
[3] Tamura N, Fujimoto M, Kamino M, et al. Mechanical stability of Sn-Co alloy anodes for lithium secondary batteries [J]. Electrochimica Acta, 2004, 49(12): 1949-1956.
[4] Xia Y Y, Sakai T, Takuya F, et al. Flake Cu-Sn alloys as negative electrode materials for rechargeable lithium batteries [J]. Journal of The Electrochemical Society, 2001, 148(5): A471-A 481.
[5] Mao O, Dahn J R. Mechanically alloyed Sn-Fe(-C) powders as anode materials for Li-ion batteries-II. The SnFe system [J]. Journal of The Electrochemical Society, 1999, 146(2): 414-422.
[6] http://www.sony.net/SonyInfo/News/Press/200502/05-006E/, last accessed: February 7, 2011.
[7] Chen Z X, Qian J F, Cao Y L, et al. Preparation and electrochemical performance of Sn-Co-C composite as anode material for Li-ion batteries [J]. Journal of Power Sources, 2009, 189(1): 730-732.
[8] Ferguson P, Todd A, Dahn J. Comparison of mechanically alloyed and sputtered tin-cobalt-carbon as an anode material for lithium-ion batteries [J]. Electrochemistry Communications, 2008, 1(10): 25-31.
[9] Huang T, Yao Y, Wei Z, et al. Sn-Co-artificial graphite composite as anode material for rechargeable lithium batteries [J]. Electrochimica Acta, 2010, 1(56): 476-482.
[10] Hassoun J , Mulas G, Panero S, et al. Ternary Sn-Co-C Li-ion battery electrode material prepared by high energy ball milling [J]. Electrochemistry Communications, 2007, 8(9): 2075-2081.
[11] Cui W J, Wang F, Xia Y Y, et al. Nanostructural CoSnC anode prepared by CoSnO3 with improved cyclability for high-performance Li-ion batteries [J]. Electrochimica Acta, 2011, 13(56): 4812-4818.
[12] Todd A, Ferguson P, Dahn J, et al. Tin-based materials as negative electrodes for Li-ion batteries: Combinatorial approaches and mechanical methods [J]. International Journal of Energy Research, 2010, 6(34): 535-555.
[13] He J C, Zhao H L, Wang M W, et al. Preparation and characterization of Co-Sn-C anodes for Li-ion batteries [J]. Materials Science and Engineering: B, 2010, 171(1/3): 35-39.
[14] Chang Y Q (常玉清), Huang L (黄令), Sun S G (孙世刚). Electrodeposition and electrochemical properties of ternary Sn-Co-Zn alloy electrodes as anodes for lithium-ion batteries [J]. Acta Physico-Chimica Sinica (物理化学学报), 2010, 26(3): 561-566.
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