•  
  •  
 

Corresponding Author

Pei-Kang SHEN(pkshen@gxu.edu.cn)

Abstract

The Fe3O4/Carbon composites have been synthesized through coprecipitation pathway and by insitu aniline polymerization as a carbon source. Structural characterization and morphological study of the composites were investigated by using XRD, SEM and TEM techniques. The results showed that the nanosized Fe3O4 particles (40 ~ 80 nm) were encapsulated in the amorphous carbon. During the electrochemical tests, the Fe3O4/C composites exhibited high capaticity and excellent cycle ability, the retention of capaticity was about 1000 mAh?g-1 after 30 cycles of charge/discharge tests at 50 mA?g-1.

Graphical Abstract

Keywords

Fe3O4, negative materials, Li-ion batteries, amorphous carbon

Publication Date

2013-02-28

Online Available Date

2012-02-01

Revised Date

2012-01-14

Received Date

2011-12-20

References

[1] Scrosati B. Recent advances in lithium ion battery materials [J]. Elecrtochimica Acta, 2000, 45 (8): 2461-2466.

[2] Broussely M. Lithiun batteries R&D activities in Europe [J]. Journal of Power Sources, 1999, 81-82: 137-139.

[3] Owens B B, Smyrl W H, Xu J J. R&D on lithium batteries in the USA: high-energy electrode materials [J]. Journal of Power Sources, 1999, 81-82: 150-155.

[4] Mitra S, Poizot P, Finke A, et al. Growth and electrochemical characterization versus lithium of Fe3O4 electrodes made by electrodeposition [J]. Advanced Functional Materials, 2006, 16(17): 2281-2287.

[5] Taberna P L, Mitra S, Poizot P, et al. High rate capabilities Fe3O4-based Cu nano-architectured electrodes for lithium-ion battery applications [J]. Nature Materials, 2006, 5(7): 567-573.

[6] Debart A, Dupont L, Poizot P, et al. Transmission electron microscopy study of the reactivity mechanism of tailor-Made CuO particles toward Lithium [J]. Journal of The Electrochemical Society, 2001, 148(11): A1266-A1274

[7] Balaya P, Li H, Kienle L, et al. Fully reversible homogeneous and heterogeneous Li storage in RuO2 with high capacity [J]. Advanced Functional Materials, 2003, 13(8): 621-625.

[8] Delmer O, Balaya P, Kienle L, et al. Enhanced potential of amorphous electrode materials: case study of RuO2 [J]. Advanced Materials, 2008, 20(3): 501-505.

[9] Yuan S M, Li J X, Yang L T, et al. Preparation and lithium storage performances of mesoporous Fe3O4@C microcapsules [J]. ACS Applied Materials & Interfaces 2011, 3(3): 705-709.

[10] Zhou G M, Wang D W, Li F, et al. Graphene-wrapped Fe3O4 anode material with improved reversible capacity and cyclic stability for lithium ion batteries [J]. Chemistry of Materials, 2010, 22(18): 5306-5313.

[11] Muraliganth T, Murugan A V, Manthiram A. Facile synthesis of carbon-decorated single-crystalline Fe3O4 nanowires and their application as high performance anode in lithium ion batteries [J]. Chemical Communications, 2009, 47: 7360-7362.

[12] Lou X W, Li C M and Archer L A A. Designed synthesis of coaxial SnO2@carbon hollow nanospheres for highly reversible lithium storage [J]. Advanced Materials, 2009, 21(24): 2536-2539.

[13] Hu Y S, Rezan D C, Titirici M M, et al. Superior storage performance of a Si@SiOx/C nanocomposite as anode material for lithium-ion batteries [J]. Angewandte Chemie International Edition, 2008, 47(9): 1645-1649.

[14] Yuan S M, Zhou Z and Li G. Structural evolution from mesoporous α-Fe2O3 to Fe3O4@C and γ-Fe2O3 nanospheres and their lithium storage performances [J]. CrystEngComm, 2011, 13(14): 4709-4713.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.