Abstract
The Fe3O4/Carbon composites have been synthesized through coprecipitation pathway and by insitu aniline polymerization as a carbon source. Structural characterization and morphological study of the composites were investigated by using XRD, SEM and TEM techniques. The results showed that the nanosized Fe3O4 particles (40 ~ 80 nm) were encapsulated in the amorphous carbon. During the electrochemical tests, the Fe3O4/C composites exhibited high capaticity and excellent cycle ability, the retention of capaticity was about 1000 mAh?g-1 after 30 cycles of charge/discharge tests at 50 mA?g-1.
Graphical Abstract
Keywords
Fe3O4, negative materials, Li-ion batteries, amorphous carbon
Publication Date
2013-02-28
Online Available Date
2012-02-01
Revised Date
2012-01-14
Received Date
2011-12-20
Recommended Citation
Jun-Jie CAI, Shu YAO, Ze-Sheng LI, Hui MENG, Pei-Kang SHEN.
Electrochemical Performance of Fe3O4/C Composites as Negative Material for Lithium-ion Batteries[J]. Journal of Electrochemistry,
2013
,
19(1): Article 14.
DOI: 10.61558/2993-074X.2940
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol19/iss1/14
References
[1] Scrosati B. Recent advances in lithium ion battery materials [J]. Elecrtochimica Acta, 2000, 45 (8): 2461-2466.
[2] Broussely M. Lithiun batteries R&D activities in Europe [J]. Journal of Power Sources, 1999, 81-82: 137-139.
[3] Owens B B, Smyrl W H, Xu J J. R&D on lithium batteries in the USA: high-energy electrode materials [J]. Journal of Power Sources, 1999, 81-82: 150-155.
[4] Mitra S, Poizot P, Finke A, et al. Growth and electrochemical characterization versus lithium of Fe3O4 electrodes made by electrodeposition [J]. Advanced Functional Materials, 2006, 16(17): 2281-2287.
[5] Taberna P L, Mitra S, Poizot P, et al. High rate capabilities Fe3O4-based Cu nano-architectured electrodes for lithium-ion battery applications [J]. Nature Materials, 2006, 5(7): 567-573.
[6] Debart A, Dupont L, Poizot P, et al. Transmission electron microscopy study of the reactivity mechanism of tailor-Made CuO particles toward Lithium [J]. Journal of The Electrochemical Society, 2001, 148(11): A1266-A1274
[7] Balaya P, Li H, Kienle L, et al. Fully reversible homogeneous and heterogeneous Li storage in RuO2 with high capacity [J]. Advanced Functional Materials, 2003, 13(8): 621-625.
[8] Delmer O, Balaya P, Kienle L, et al. Enhanced potential of amorphous electrode materials: case study of RuO2 [J]. Advanced Materials, 2008, 20(3): 501-505.
[9] Yuan S M, Li J X, Yang L T, et al. Preparation and lithium storage performances of mesoporous Fe3O4@C microcapsules [J]. ACS Applied Materials & Interfaces 2011, 3(3): 705-709.
[10] Zhou G M, Wang D W, Li F, et al. Graphene-wrapped Fe3O4 anode material with improved reversible capacity and cyclic stability for lithium ion batteries [J]. Chemistry of Materials, 2010, 22(18): 5306-5313.
[11] Muraliganth T, Murugan A V, Manthiram A. Facile synthesis of carbon-decorated single-crystalline Fe3O4 nanowires and their application as high performance anode in lithium ion batteries [J]. Chemical Communications, 2009, 47: 7360-7362.
[12] Lou X W, Li C M and Archer L A A. Designed synthesis of coaxial SnO2@carbon hollow nanospheres for highly reversible lithium storage [J]. Advanced Materials, 2009, 21(24): 2536-2539.
[13] Hu Y S, Rezan D C, Titirici M M, et al. Superior storage performance of a Si@SiOx/C nanocomposite as anode material for lithium-ion batteries [J]. Angewandte Chemie International Edition, 2008, 47(9): 1645-1649.
[14] Yuan S M, Zhou Z and Li G. Structural evolution from mesoporous α-Fe2O3 to Fe3O4@C and γ-Fe2O3 nanospheres and their lithium storage performances [J]. CrystEngComm, 2011, 13(14): 4709-4713.
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