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Corresponding Author

Gui-Chang LIU

Abstract

Carbon coated tin power was prepared by decomposing glucose applying a hydrothermal method, and was further used as the active material for negative electrode of lithium secondary battery. Charge-discharge tests show that the carbon coated tin electrode with the addition of 5 wt.% acetylene black as a conductive agent could obtain an initial discharge capacity of 967 mAh.g-1 and a discharge capacity of 362 mAh.g-1 after 50 cycles, which is much higher than that of tin electrode (166 mAh.g-1 after 50 cycles). The coated carbon hinders the agglomeration of tin powder, reduces the irreversible capacity loss of tin; the addition of acetylene black could reduce the impedance between the electrode and the electrolyte, therefore, improve the transfer property of lithium ions and the electrons within the electrode, which contribute to the higher initial discharge capacity.

Graphical Abstract

Keywords

lithium-ion battery, carbon coating, tin, cycle performance

Publication Date

2013-04-28

Online Available Date

2012-03-09

Revised Date

2012-02-09

Received Date

2012-01-09

References

[1] Zhang T, Fu L J, Gao J, et al. Nanosized tin anode prepared by laser-induced vapor deposition for lithium ion battery [J]. Journal of Power Sources, 2007, 174(2): 770-773.

[2] Bazin L, Mitra S, Taberna P L, et al. High rate capability pure Sn-based nano-architectured electrode assembly for rechargeable lithium batteries [J]. Journal of Power Sources, 2009, 188(2): 578-582.

[3] Liu S, Li Q, Chen Y X, et al. Carbon-coated copper-tin alloy anode material for lithium ion batteries [J]. Journal of Alloys and Compounds, 2009, 478(1/2): 694-698.

[4] Zou L, Gan L, Kang F Y, et al. Sn/C non-woven film prepared by electrospinning as anode materials for lithium ion batteries [J]. Journal of Power Sources, 2010, 195(4): 1216-1220.

[5] Yu H W, Hu S J, Hou X H, et al. Electrochemical performance of tin-aluminum thin film anode for lithium ion battery [M]// Gu Z W, Han Y F, Pan F H, et al. Materials Science Forum, Switzerland, Trans Tech Publications Ltd, 2009, 610-613: 467-471.

[6] Li J, Le D B, Ferguson P P, et al. Lithium polyacrylate as a binder for tin-cobalt-carbon negative electrodes in lithium-ion batteries [J]. Electrochimica Acta, 2010, 55(8): 2991-2995.

[7] Song S W, Baek S W. Surface layer formation on Sn anode: ATR FTIR spectroscopic characterization [J]. Electrochimica Acta, 2009, 54(4): 1312-1318.

[8] Li H Q, Zhou H S. Enhancing the performances of Li-ion batteries by carbon-coating: Present and future [J]. Chemical Communications, 2012, 48(9): 1201-1217.

[9] Wang Z, Tian W H, Liu X H, et al. Synthesis and electrochemical performances of amorphous carbon-coated Sn-Sb particles as anode material for lithium-ion batteries [J]. Journal of Solid State Chemistry, 2007, 180(12): 3360-3365.

[10] Du Z J, Zhang S C, Jiang T, et al. Preparation and characterization of three-dimensional tin thin-film anode with good cycle performance [J]. Electrochimica Acta, 2010, 55(10): 3537-3541.

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