Abstract
Silver was deposited homogeneously on the surface of polyamide fabric by electroless plating without activation and sensitization. The electroless silver plating process was optimized with the orthogonal array testing strategy. It is found that the optimum conditions are the electroless plating time of 50 min with the concentrations of silver nitrate, sodium hydroxide and ammonium hydroxide being 14 g·L-1, 6 g·L-1 and 130 mL·L-1, respectively. The surface morphologies, compositions, and phases of fabric samples were characterized by scanning electron microscopy and energy-dispersive X-ray spectrometry (SEM-EDS), X-ray diffraction (XRD). The wear-resisting property was tested by friction fastness test machine. The results show that the gain size of silver plating layer is 28.9 nm with the preferred orientation along direction (111) and the good wear resistance.
Keywords
without activation and sensitization, electroless silver, nylon fabric, orthogonal test, chitosan
Publication Date
2013-06-28
Online Available Date
2012-08-02
Revised Date
2012-07-27
Received Date
2012-06-11
Recommended Citation
Bo Lian WANG, Ya ping ZHAO, Zai Sheng CAI.
Optimization of Electroless Silver Plating Process on Fabric Surface without Activation and Sensitization[J]. Journal of Electrochemistry,
2013
,
19(3): Article 14.
DOI: 10.61558/2993-074X.2961
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol19/iss3/14
References
[1] Li L L, Yu D, Wang L, et al. Electroless silver plating on the PET fabrics modified with 3-mercaptopropyltriethoxysilane[J]. Journal of Applied Polymer Science, 2012, 124(3): 1912-1918.
[2] Calvert P, Duggal D, Patra P, et al. Conducting polymer and conducting composite strain sensors on textiles[J]. Molecular Crystals and Liquid Crystals. 2008, 484(1): 291-302.
[3] Chen X H(陈小华), Chen Z Z(陈宗璋). Preparation of coating of carbon nanotube with silver and SEM Study[J]. Jourrml of Hunan University(Natural Sciences Edition)(湖南大学学报 自然科学版). 1999, 26(6): 14-17.
[4] Nair B K R, Choi J, Harold M P. Electroless plating and permeation features of Pd and Pd/Ag hollow fiber composite membranes[J]. Journal of membrane science. 2007, 288(1): 67-84.
[5] You Y X, Ye Y, Su Y J, et al. Preparation and field emission properties of Ag-CNTs by electroless plating[J]. Advanced Materials Research, 2011, 148-149: 983-986.
[6] Lee Y, Kim E, Kim K, et al. Polyaniline effect on the conductivity of the PMMA/Ag hybrid composite[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2012, 396(20): 195-202.
[7] Ye Z Y(叶肇云), Sun Y Q(孙亚勤). Spectrophotometric determination of Sn(II) content in DTPA-HSA kit[J]. Journal of Isotopes(同位素). 1999, 12(2): 95-99.
[8] Byeon J H, Ko B J, Hwang J. Catalytic activation of activated carbon fibers via palladium aerosol nanoparticles for use in electroless silver deposition[J]. The Journal of Physical Chemistry C, 2008, 112(10): 3627-3632.
[9] Jeon Y M, Gong M S, Cho H N. Preparation of silver/PMMA beads via the in sito reduction of a silver alkylcarbamate complex[J]. Macromolecular Research, 2009, 17(1): 2-4.
[10] Zhao W, Zhang Q, Zhang H, et al. Preparation of PS/Ag microspheres and its application in microwave absorbing coating[J]. Journal of Alloys and Compounds, 2009, 473(1/2): 206-211.
[11] You M, Zhang L L, Gong Z P, et al. On the properties of conductive adhesive filled with electroless silver plated flake graphite[J]. Key Engineering Materials, 2008, 373: 220-223.
[12] Zhang H. Silver plating on hollow glass microsphere and coating finishing of PET/cotton fabric[J]. Journal of Industrial Textiles, 2012, 42(3): 283-296
[13] Lien W F, Huang P C, Tseng S C, et al. Electroless silver plating on tetraethoxy silane-bridged fiber glass[J]. Applied Surface Science, 2011, 258(7): 2246-2254.
[14] Juang R S, Shao H J. Effect of pH on competitive adsorption of Cu(II), Ni(II), and Zn(II) from water onto chitosan beads[J]. Adsorption, 2002, 8(1): 71-78.
[15] Xu Y(许勇), Hong H(洪华), Qian Y(钱颖), et al. Preparation and characteration of biomedical chitosan films[J]. Joumal of Functional Polymers(功能高分子学报), 2004, 17(1): 55-60.
[16] Chen X(陈新), Huang Y F(黄郁芳). Influence of crosslinking agent content on structure and properties of glutaraldehyde crosslinked chitosan membranes[J]. Acta Chimica Sinica(化学学报), 2000, 58(12): 1654-1659.
[17] Dang M Y(党明岩), Zhang Y A(张廷安), Wang P(王娉), et al. Crosslinked chitosan resin[M]. Beijing, Chemical Industry Press (化学工业出版社), 2009: 196-202.
[18] Meng Y(孟云), Zhao Y P(赵亚萍), Bian X H(卞学海), et al. Preparation of silver/polyaniline/polyamide conductive fabric and its properties[J]. Dyeing and Finishing (印染), 2011, 37(19): 1-4.
[19] Gan X P(甘雪萍). A study on the preparation and commerical test of conductive PET fabrics used for electromagnetic shielding[D]. Shanghai: Shanghai Jiao Tong University(上海: 上海交通大学), 2007.
[20] Schaefers S, Rast L, Stanishevsky A. Electroless silver plating on spin-coated silver nanoparticle seed layers[J]. Materials Letters, 2006, 60(5): 706-709.
[21] Tschöpe A. Grain size-dependent electrical conductivity of polycrystalline cerium oxide II: Space charge model[J]. Solid State Ionics, 2001, 139(3): 267-280.
[22] Huang P, Lin J, Li Z, et al. A general strategy for metallic nanocrystals synthesis in organic medium[J]. Chemical Communications, 2010, 46(26): 4800-4802.
[23] Wei L L(魏丽丽), Xu S M(徐盛明), Xu g(徐刚), et al. Effects of surfactants on dispersive performance of ultrafine silver powder[J]. The Chinese Journal of Nonferrous Metals(中国有色金属学报), 2009, 19(3): 595-600.
[24] Weckhuysen B M, Van Der Voort P, Catana G. Spectroscopy of transition metal ions on surfaces[M]. Leuven Belgium: Leuven University Press, 2000: Chapter 1.
[25] Xu S K(许书楷), Yang F Z(杨防祖), Zhou S M(周绍民). Effect of deposition conditions on the texture of zinc deposits [J]. Journal of Electrochemistry(电化学), 1995(4): 408-414.
Included in
Materials Chemistry Commons, Nanoscience and Nanotechnology Commons, Physical Chemistry Commons