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Abstract

Ordered monolayers of S- and N-containing amphipathic corrosion inhibitors were depoitod onto the surfaces of carbon steel electrode with super-molecular assembly technique. The effect of molecular aggregation of monolayers on carbon steel corrosion in 0. 05 mol dl ̄(-3)H_2SO_4 and the mechanisms of these inhibitors were discussed in details. It was found that the transport of hydrated hydrogen ion to the surface of steel depends strongly on the inhibitor molecular aggregation in the monolayers.

Keywords

Super-molecular assembly, LB monolayer, Metal corrosion inhibitor, Corrosion

Publication Date

1996-02-28

Online Available Date

1996-02-28

Revised Date

1996-02-28

Received Date

1996-02-28

References

1CarterFL.MolecularElectronicDevices,1stedNewYork,NY:MarcelDekkerInc.,19822KuhnH.Functionalizedmonolayerassemblymuniplation.ThinSolidFilms,1983,99:13BinksBP.Insolublemonolayersofweaklylonisinglowmolarmassmaterialsandtheirdepositiontoformlangmuirblodgettmultilayers.Adv.inColloidandInterfaceSci.,1991,34:3434TrabanelliG.Inhibitors──Anoldremedyforanewchallenge.Corrosion,1991,47:4105XingW,ShanY,GuoDetal.Mechanismofinhibitionbystearicacidlangmuir-blodgettmonolayers.Corrosion,1995,51:456KendigMW,MansfeldF,TsaiS.DeterminationofthelongtermcorrosionbehaviorofcoartingsteelwithA.C.impedancemeasurements.Corros.Sci.,1983,23:3177SchweisbergDP,AshworthV.TheInhibitionofthecorrsionofpureironinsulphuricacidbyn-alkylquaternaryammoniumlodides.Corros.Sic.,1988,28:5398KorytaJ,DvorakJ.PrinciplesofElectrochemstry,1stedNewYork,NY:Willey,1987

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