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Abstract

The properties of CaCl_2 SEI covered on the ca electrode surface in thionyl chloride, the influence of various salts in thionyl chloride on the porformance of the Ca anede and carbon cathode, and the function of the additive CuCl_2 and CuBr_2 to cathode in the improvement of the cathode performance were studied by AC impedance, constant current discharge, and SEM. As a result,the Ca-SOCl_2 cell was able to discharge at 50 mA·cm ̄(-2)and the capacity reached 17.5 mAh ·cm ̄(-2).

Keywords

Callcium-thionyl chloride cells, Calcium electrode, Thionyl chloride

Publication Date

1996-02-28

Online Available Date

1996-02-28

Revised Date

1996-02-28

Received Date

1996-02-28

References

1MeitavA,PeledE.SolidElectrolyteInterphase(SEI)Electrode.J.Electrochem.Sor.,1981,128:8252PeledE.Advancedcalcium-thionylchloridehigh-powerbattery.AD-A207.612,19893ChadesWWalker.AReviewoftheCalchurnThionylChlorideElectrochemicalSystem.AD-A261,321,19914陈猛等。钙/亚硫酰氯电池阴极工艺研究。电源技术,1994,18(5);24

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