Abstract
Because of its great importance both in electrocatalysis and C1 chemistry applications, the adsorption of CO on metallic electrodes such as Pt, Pd, Au, Ag, RhF￣[1～2], etc. has been extensively studied by in situ infrared spectroscopy Since 1981. In all these studies only three types of CO adsorbates, i. e. , linear (2 090～2 000 cm￣(-1)), bridgrd (2 000～1 900 cm￣(-1)) or multi-bonded (1900～1 800 cm￣(-1)) species, were identified. A different absorbate, twin CO on rhodium ((Rh (CO)2) , does exist on the solid/gas interface of highly dispersed Rh or Rhn clusters[3～4] on supports,this species originating a doublet at 2100 and 2030 cm￣(-1) for its symmetrical and asymmetrical stretch modes, respectively. To our knowledge, this doublet has not been reported yet for the Rh/electrolyre interface.
Keywords
In situ multi-step FTIRS, Surface processes, Twin adsorbates, Carbon References
Publication Date
1996-02-28
Online Available Date
1996-02-28
Revised Date
1996-02-28
Received Date
1996-02-28
Recommended Citation
Wenfeng Lin, Shigang Sun.
FTIS Observation of Twin Adsorbates of CO on Rh Electrode in Acid Solution[J]. Journal of Electrochemistry,
1996
,
2(1): Article 9.
DOI: 10.61558/2993-074X.3050
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol2/iss1/9
References
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