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Corresponding Author

Zhaoe Lu

Abstract

The authors investigated the electrochemical reduction of oxygen to hydrogen peroxide in 0.05 mol/L H 2SO 4 solution by the trickle bed electrode using graphite chip. The bed dimension was 14×5×0.6 cm. The current efficiency and the concentration of H 2O 2 in the catholyte were determined at various current strengths and various rates of adding the electrolyte. The proper current was 0.15 A. i.e. the current density was 2.1 mA/cm 2 vertical cross section area of the bed. The concentration of H 2O 2 reached 7×10 -3 mol/L with the current efficiency of 0.2. If the concentration of H 2O 2 reduced to 4×10 -3 mol/L, the current efficiency might increase to 0.4.

Keywords

Hydrogen peroxide, Electroreduction, Oxygen electrode, Trickle bed reactors

Publication Date

1996-05-28

Online Available Date

1996-05-28

Revised Date

1996-05-28

Received Date

1996-05-28

References

1OlomanC,WatkinsonAP.Hydrogenperoxideproductionintrickle-bedelectrochemicalreactors.J.Ap-pliedElectrochem,1979,9:1172DavisonJB,KacsirJM,Peerce-LandersPJetal.AvoltammetricinvestigationofoxygenreductioninatricklebedcelusinggraphitechipandRVCcathodes.J.Electrochem.Soc.,1983,130(7):14973SpalekO,BaloghK.Generationofhydrogenperoxidebyreductionofoxygeninsemi-hydrophorbictrick-leelectrodes.Colect.Czech.Chem.Commun.,1991,56:3094SpalekO,BaloghK.Reductionofoxygentoperoxideinatrickleelectrode.Colect.Czech.Chem.Com-mun.,1989,54:15645SpalekO.Calculationofpotentialandconcentrationgradientsintrickle-bedelectridesproducinghydrogenperoxide.Colect.Czech.Chem.Commun.,1986,51:18836SabupovFZ,TapacevuchMP,BypshmeunPX.Themechanismofthereductionofoxygenonpyrolyticgraphiteandglassycarboninacidandalkalinesolutions.Elektrokhimiya,1970,6:1130

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