Abstract
The authors investigated the electrochemical reduction of oxygen to hydrogen peroxide in 0.05 mol/L H 2SO 4 solution by the trickle bed electrode using graphite chip. The bed dimension was 14×5×0.6 cm. The current efficiency and the concentration of H 2O 2 in the catholyte were determined at various current strengths and various rates of adding the electrolyte. The proper current was 0.15 A. i.e. the current density was 2.1 mA/cm 2 vertical cross section area of the bed. The concentration of H 2O 2 reached 7×10 -3 mol/L with the current efficiency of 0.2. If the concentration of H 2O 2 reduced to 4×10 -3 mol/L, the current efficiency might increase to 0.4.
Keywords
Hydrogen peroxide, Electroreduction, Oxygen electrode, Trickle bed reactors
Publication Date
1996-05-28
Online Available Date
1996-05-28
Revised Date
1996-05-28
Received Date
1996-05-28
Recommended Citation
Zhaoe Lu, Guanyong Zhang, Tiangeng Zhong, Guonu Fang.
The Reduction of Oxygen to Hydrogen Peroxide in an Acidic Trickle Bed Cell Using Graphite Chip Cathode[J]. Journal of Electrochemistry,
1996
,
2(2): Article 18.
DOI: 10.61558/2993-074X.3078
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol2/iss2/18
References
1OlomanC,WatkinsonAP.Hydrogenperoxideproductionintrickle-bedelectrochemicalreactors.J.Ap-pliedElectrochem,1979,9:1172DavisonJB,KacsirJM,Peerce-LandersPJetal.AvoltammetricinvestigationofoxygenreductioninatricklebedcelusinggraphitechipandRVCcathodes.J.Electrochem.Soc.,1983,130(7):14973SpalekO,BaloghK.Generationofhydrogenperoxidebyreductionofoxygeninsemi-hydrophorbictrick-leelectrodes.Colect.Czech.Chem.Commun.,1991,56:3094SpalekO,BaloghK.Reductionofoxygentoperoxideinatrickleelectrode.Colect.Czech.Chem.Com-mun.,1989,54:15645SpalekO.Calculationofpotentialandconcentrationgradientsintrickle-bedelectridesproducinghydrogenperoxide.Colect.Czech.Chem.Commun.,1986,51:18836SabupovFZ,TapacevuchMP,BypshmeunPX.Themechanismofthereductionofoxygenonpyrolyticgraphiteandglassycarboninacidandalkalinesolutions.Elektrokhimiya,1970,6:1130
Included in
Catalysis and Reaction Engineering Commons, Engineering Science and Materials Commons, Materials Chemistry Commons, Nanoscience and Nanotechnology Commons, Physical Chemistry Commons, Power and Energy Commons, Semiconductor and Optical Materials Commons