Polarographic and Voltammetric Behaviour of Complex of Ciprofloxacin with Manganese

Authors

Jialing Zhang, Department of Chemistry, Shanxi University, Taiyuan 030006, China
Huizhi Fan, Department of Chemistry, Shanxi University, Taiyuan 030006, China
Jinghao Pan, Department of Chemistry, Shanxi University, Taiyuan 030006, China

Corresponding Author

Jinghao Pan

Abstract

In 0.1 mol·L^-1 NH₃NH₄Cl buffer solution (pH 9.2) ,a sensitive reduction peak of complex of ciprofloxacin (CPFX) with manganese (Mn) was obtained by single sweep oscillopolarograph. The peak potential (E_p) is -1.61 V (vs.SCE). The peak current (i_p) is proportional to the concentration of Mn(Ⅱ) over the range of 5×10^-6 ～2×10^-5 mol·L^-1. It is possible to be applied to the determination of Mn(Ⅱ). The polarographyic and voltammetric behaviour of complex was studied in detail. The ratio of CPFX∶Mn in the complex was 2:1. The electrode reaction mechanism was discussed.

Keywords

Ciprofloxacin, Mn(Ⅱ), Complex, Polarography, Voltammetry, Reduction mechanism

DOI Link

https://doi.org/10.61558/2993-074X.3080

Publication Date

1996-05-28

Online Available Date

1996-05-28

Revised Date

1996-02-18

Received Date

1995-12-15

Recommended Citation

Jialing Zhang, Huizhi Fan, Jinghao Pan. Polarographic and Voltammetric Behaviour of Complex of Ciprofloxacin with Manganese[J]. Journal of Electrochemistry, 1996 , 2(2): 229-232.
DOI: 10.61558/2993-074X.3080
Available at: https://jelectrochem.xmu.edu.cn/journal/vol2/iss2/20