Oxygen Charge transfer reaction at the Pt/YSZ interface

Authors

Yi Jiang, Department of chemistry, Lanzhou University, Lanzhou 730000;
Wenzhao Li, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023;
Jingwang Yan, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023;
Shizhong Wang, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023;

Abstract

Oxygen Charge transfer reaction has been investigated by various degrees of potential polarization at the Pt/YSZ interface. Anodic and cathodic charge transfer coefficients were found to be unity over the wide range of oxygen partial pressures and temperatures. While the exchange current density of the interface was found dependent on the partial pressure of oxygen in accordance with the relation: i 0=2FK r(K O 2 P O 2 ) 1/4 (1+K O 2 P O 2 ) 1/2 . Several important parameters, such as electrochemical rate constant, equilibrium constant of oxygen adsorption on Pt surface had also been extracted.

Keywords

Pt electrode, YSZ solid electrolyte, Oxygen charge transfer reaction.

DOI Link

https://doi.org/10.61558/2993-074X.3068

Publication Date

1996-05-28

Online Available Date

1996-05-28

Revised Date

1996-05-28

Received Date

1996-05-28

Recommended Citation

Yi Jiang, Wenzhao Li, Jingwang Yan, Shizhong Wang. Oxygen Charge transfer reaction at the Pt/YSZ interface[J]. Journal of Electrochemistry, 1996 , 2(2): Article 8.
DOI: 10.61558/2993-074X.3068
Available at: https://jelectrochem.xmu.edu.cn/journal/vol2/iss2/8

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