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Corresponding Author

Fupjng Zhang

Abstract

The charge and discharge reaction of Li/LiNi0.3Co0.7O2 battery have been studied by using CV,CT,XRD and GCP. It is shown that the discharge capacity of the cell reaches 120-140 mA·h·g-1 in the 4.30-3.00 V in 1 mol/L LiClO4/PC electrolyte system. The discharge mechanism involve a two-step Li+ intercalation reaction. The thermodynamic data such as ΔG,ΔS, ΔH, of the reaction are given. Furthermore, the changes of the D or σi of Li+ with its composition have been discussed.

Keywords

Lithium Battery, Lithium Nickel Cobalt Oxide, Intercalation Reaction

Publication Date

1996-08-28

Online Available Date

1996-08-28

Revised Date

1996-05-16

Received Date

1995-11-24

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