Abstract
The diffusion coefficients of protons moving in the Ni(OH)2 electrodes have being investigated by constant current,cyclic voltammetry and potential step technineques.The electrodes were prepared by cathodic deposition and their active material contained 0~53% cobalt.It was found that the diffusion coefficients are about 10(-9)~10(-10) cm2/s during charging and about 10(-11) cm2/s during discharging.Moreover the value increases with the increacing content of Co in the electrodes.During the calculation,the relevant fomulars were modified especially the wrong fomular for constant current methode.
Keywords
Co, Ni(OH)2 electrode, Diffusion coefficient
Publication Date
1996-08-28
Online Available Date
1996-08-28
Revised Date
1996-08-28
Received Date
1996-08-28
Recommended Citation
Xiaoyan Cao, Zuoxiang Zhou, Huatang Yuan, Yunshi Zhang.
The Effect of Co on the Proton Diffusion Coefficient for the Ni(OH)2 Electrodes[J]. Journal of Electrochemistry,
1996
,
2(3): 319-326.
DOI: 10.61558/2993-074X.1343
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol2/iss3/14
References
1曹晓燕,毛立彩,周作祥.氢氧化镍电极及其添加剂.电池,1994,24(5):236~2392ArmstrongRD,BriggsGWD,CharlesEA.Someeffectsoftheadditionofcobalttonickelhydroxideelectrode.J.Appl.Electrochem.,1988,18:215~2193ArmstrongRD,CharlesEA.Someeffectsofcobalthydroxideupontheelectrochemicalbehaviourofnickelhydroxideelectrodes.J.PowerSources,1989,25:89~974ArmstrongRD,CharlesEA.SomeaspectsoftheA.C.impedancebehaviourofnickelhydroxideandnickel/cobalthydroxideelectrodesinalkalinesolution.J.PowerSources,1989,27:15~275DelmasC,FaureC,BorthomieuY.Theeffectsofcobaltonthechemicalandelectrochemicalbehaviourofthenicklehydroxideelectrode.Mater.Sci.Eng.,1992,B13:89~966FaureC,DelmasC.Electrochemicalbehaviourofα-cobaltednickelhydroxideelectrodes.J.PowerSources,1991,36:497~5067OshitaniM,TakayamaT,TakashimaK.TsujiSh.Astudyontheswellingofasinterednickelhydroxideelectrode.J.Appl.Electrochem.,1986,16:403~4128DavolioD,SoragniE.Dischargebehaviourofplanenickelhydroxideelectrodes.Electrochim.Acta,1983,28(3):335~3399B,OC.1976,12:1161~116310PortemerF,DelahayeVidalA.FiglarzM.Characterizationofactivematerialdepositedatthenickelhydroxideelectrodebyelectrochemicalimpregnation.J.Electrochem.1992,139(3):671~67811GreavesC,ThomasMA.Structuralandelectrochemicalcharacteristicsofplastic(PTFE)bondednickelhydroxideelectrodes,J.PowerSources,1984,12:195~20212BensonP,BriggsGWD,Wynne-JonesWFK,Thecobalthydroxideelectrode──Ⅰ.Structureand phasetransitionofthehydroxides.Electrochem.Acta,1964,9:275~28013CornilsenBC,ShanXY,LoysellePL.Structuralcomparisonofnickelelectrodesandprecursorphases.J.PowerSiurces,1990,29:453~46614GuntherRG,GrossS.Thenickelelectrode.Proceedingsofthesymposium.TheElectrochem.Soc.,198215MacArthurDM.Thehydratednickelhydroxideelectrodepotentialsweepexperiments.J.Electrochem.Soc.,1970,117(4):422~42616田昭武。电化学研究方法。北京:科学出版社,1984:23217BarnardR,RandellCF,TyeFL.Strudiesconcerningchargednickelhydroxideelectrodes.Ⅰ.Measurementofreversiblepotentials.J.Appl.Electrochem.1980(10):109~12518BardAllenJ.Encyclopediaofelectrochemistryoftheelements.VolⅢNewYork:MarcelDekker,Inc,1975:5219印永嘉等。物理化学简明手册。北京:高等教育出版社。1988:21820MacArthurDM.Theprotondiffusioncoefficientforthenickelhydroxideelectrode.J.Electrochem.Soc.,1970,117(6):729~73321王洁,金承和,江志裕。Ni(OH)_2电极在碱液中的电化学行为。电池,1989,2:36~41
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