An ESR Study of Free Radicals in Electroreduction Process of Allyl Alcohol

Authors

Jindong Zhang, Dept. of Chem, and Chem. Eng., Hunan University, Changsha 410082
Yafei Kuang, Dept. of Chem, and Chem. Eng., Hunan University, Changsha 410082
Shukun Huang, Dept. of Chem, and Chem. Eng., Hunan University, Changsha 410082
Naixian Xie, Dept. of Chem, and Chem. Eng., Hunan University, Changsha 410082
Fengzhen Wang, Centre Laburatury, Centre South University of Technology, Changsha 410083
Dewen Chen, Inst. of Chem., Academy Sinica, Beijing 100080

Corresponding Author

Jindong Zhang

Abstract

Electrochemical-ESR technique with spin trap phenyl-t-butyl nitrone(PBN)was used to study the intermediates of electroreduction of allyl alcohol at platinized platinum electrode in acidic alcohol-aqua solution. Hydrogen and allyl group and(or)propyl group radicals were identified by a hyperfine spectrum of the radical adducts, and that provided a direct evidence for the presence of these radicals in the electroreduction of allyl alcohol.

Keywords

Allyl alcohol, Electroreduction, Electrochemieal-ESR, Spin trapping

DOI Link

https://doi.org/10.61558/2993-074X.1347

Publication Date

1996-08-28

Online Available Date

1996-08-28

Revised Date

1996-04-05

Received Date

1995-12-06

Recommended Citation

Jindong Zhang, Yafei Kuang, Shukun Huang, Naixian Xie, Fengzhen Wang, Dewen Chen. An ESR Study of Free Radicals in Electroreduction Process of Allyl Alcohol[J]. Journal of Electrochemistry, 1996 , 2(3): 343-345.
DOI: 10.61558/2993-074X.1347
Available at: https://jelectrochem.xmu.edu.cn/journal/vol2/iss3/18