An ESR Study of Free Radicals in Electroreduction Process of Allyl Alcohol

Authors

Jindong Zhang, Department of Chemisry, Wuhan University, Wuhan 430072;
Yafei Kuang, Dept.of Chem.and Chem. Eng.,Hunan University,Changsha 410082)Wang Fengzhen(Centre Laboratory,Centre South University of Technology,Changsha 410083)Chen Dewen(Inst.of Chem.,Academia Sinica,Beijinq,100080;
Shukun Huang, Dept.of Chem.and Chem. Eng.,Hunan University,Changsha 410082)Wang Fengzhen(Centre Laboratory,Centre South University of Technology,Changsha 410083)Chen Dewen(Inst.of Chem.,Academia Sinica,Beijinq,100080;
Naixian Xie, Dept.of Chem.and Chem. Eng.,Hunan University,Changsha 410082)Wang Fengzhen(Centre Laboratory,Centre South University of Technology,Changsha 410083)Chen Dewen(Inst.of Chem.,Academia Sinica,Beijinq,100080;

Abstract

Electrochemical-ESR technique with spin trap phenyl-t-butyl nitrone(PBN)was used to study the intermediates of electroreduction of allyl alcohol at platinized platinum electrode in acidic alcohol-aqua solution. Hydrogen and allyl group and(or)propyl group radicals were identified by a hyperfine spectrum of the radical adducts,and that provided a direct evidence for the presence of these radicals in the electroreduction of allyl alcohol.

Keywords

Allyl alcohol, Electroreduction, Electrochemieal-ESR, Spin trapping

DOI Link

https://doi.org/10.61558/2993-074X.1347

Publication Date

1996-08-28

Online Available Date

1996-08-28

Revised Date

1996-08-28

Received Date

1996-08-28

Recommended Citation

Jindong Zhang, Yafei Kuang, Shukun Huang, Naixian Xie. An ESR Study of Free Radicals in Electroreduction Process of Allyl Alcohol[J]. Journal of Electrochemistry, 1996 , 2(3): 343-345.
DOI: 10.61558/2993-074X.1347
Available at: https://jelectrochem.xmu.edu.cn/journal/vol2/iss3/18