Abstract
Recent progresses in the studies on electrochemical and surface properties of hydrogen storage alloy materials are reviewed. This paper includes three sections: 1)Thermodynamic and kinetic studies of metal hydride electrodes, 2)Effects of micro structure and alloy elements of the materials on the electrochemical properties of the electrodes and 3)Correlation between surface properties of the alloy materials and performance of the negative electrode in the nickel metal hydride batteries.
Keywords
Nickel metal hydride batteries, Metal hydride electrodes, Hydrogen storage alloy materials, Surface properties.
Publication Date
1996-11-28
Online Available Date
1996-11-28
Revised Date
1996-11-28
Received Date
1996-11-28
Recommended Citation
Yong Yang, Jum Li, Zugeng Lin.
Progresses in the Studies on Electrochemical and Surface Properties of Hydrogen storage Alloy Materials[J]. Journal of Electrochemistry,
1996
,
2(4): Article 2.
DOI: 10.61558/2993-074X.3081
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol2/iss4/2
References
Reference1MachidaK,EnyoM,AdachiG,ShiokawaJ.TheHydrogenElectrodeReactionCharacteristicsofthinfilmElectrodeofNibasedHydrogen.ElectrochimicaActa,1984,29:8072IwakuraC,KajiyaY,YoneyamaHelal.SelfDischargeMechamismofNickleHydrogenBatteriesUsingMetalHydrideAnode.J.Electrochem.Soc.,1989,136:13513SakaiT,MutaK,MiyamuraHelal.NickleMetalHydrideBateriesUsingRareEarthBasedHydrogenStorageAloyseditedbyCoriganDAandSrinivasanSin“Proceedongsofthesymposiumonhydrogenstoragematerials,bateriesandelectochemistry”.TheElectrochem.Soc.Inc,NJ,1992,PV925,59914OvshinskySR,Fetcenko,MA,RosJ.ANickelMetalHydrideBatteryforElectricVehicles.Science,1993,260:1765IkeyaT,KumaiK,IwahoriT.MechanicalProcessforEnhancingMetalHydrideforAnodeofaNiMHSecondaryBatery.J.Electrochem.Soc.,1993,140:30826LiZ,SudaS.TheInorganicCompoundCoatingEfectontheDurabilityofCaNi5Electrode.in“Proceedingsofthesymposiumonhydrogenandhydridebatteries”editedbyBennetPDandSakaiT.TheElectrochem.Soc.Inc.,NJ,USA,1994:PV9427,78~847高学平,杨化滨,宋德瑛等.锆系Laves相贮氢合金电极性能的研究.电化学,1995,1:2988IwakuraC,MatsuokaM,KohnoT.MixingEfectofMetalOxidesonNegativeElectrodeReactionsintheNickleHydrideBatery.J.Electrochem.Soc.,1994,141(9):23069ZhangW,KumarMPS,SrinivasanSPloethHJ.ACImpendanceStudiesonMetalHydrideElectrode.J.Electrochem.Soc.,1995,142:293510KuriyamN,SakaiT,MiyamuraHetal.ElectrochemicalImpedanceSpectraandDeteriorationMechanismofMetalHydrideElectrode.J.Electrochem.Soc.,1992,139:L7211ReidMAeditedbyBennetPDandSakaiT.ImpedanceMeasurementonNi/MHCelsasFunctionsofCyCleLifeandDOD.in“Proceedingofthesymposiumonhydrogenandhydridebatteries”.TheElectrochemicalSoc.Inc.,NJ,USA,1994:PV9427,237~24812杨勇,李骏,南俊民,林祖赓.金属氢化物电极表面性能的研究.待发表13BuschowKHJ,VanMalHH.J.LesCommonMet.,1972,29:20314Wilems,J.J.G.PhilipsJ.Research,1984,39:115UchidaH,KawachiM,Gotoetal.EfectofOxidationandHydroxidationontheActivationofLaNi5-xMxAloysbyHydrogengas.Z.Phys.Chem.,1994,183:30316MeliA,ZutelA,SchlapbachL.Electrochemicalandsurfaceproperteiesoflowcost,cobaltfreeLaNi5typehydrogenaloys.J.AloyandCompounds,1993,202:8117MeliA,ZutelA,SchlapbachL.SurfaceandbulkpropertiesofLaNi5-xSixaloysfromviewpointofbateryapplication.J.AloyandCompounds,1993,190:1718NotenRHL,EinerhandREF.DaamaJIC.NonStoichiomtricHydrideFormingCompounds:AnExcellentCombinationofLongtermstabilityandhighElectrocatalyticaloys.Z.Phys.Chem.,1994,183:26719RatnakumarBV,SurampudiS,DistefanoS,HalportG,WithamC,HigttewerA,FultzB.StudiesonAB5MetalHydrideAloyswithSnadditives.in“Proceedingsofthesymposiumonhydrogenstoragematerials,bateries,andelectrochemistry”,editedbyCoriganDAandSarinevasanS.TheElectrochem.Soc.Inc.NJ,1992,PV925,57~6720TadokoroM,NoyamiM,ChikanoYetal.Developmentofhydrogenabsorbingfornicklemetalhydridesecondarybatteries.J.AloyandCompounds,1993,192:17921KumarMPS,ZhangW,PetrovKetal.SurfaceModificationbyCoatingofAloystoimprovePerformanceofMetalHydrideElectrode.in“Proceedingsofthesymposiumonhydrogenandhydridebateries”editedbyBennetPDandSakaiT.TheElectrochemicalSocietyInc.,NJ,USA,1994:PV9427,111~12322HasegawaK,OhnishiM,OshitaniMetal.NickleMetalHydrideBatery.ibid,1994,183:32523RatnakumarBV,WithamC,FultzB,HalportG.ElectrochemicalEvaluationofLaNiSnMetalHydrideAlloys.J.Electrochem.Soc.,1994:141:L8924ZhangL,OHaraTJ,MichalMG.MicrostructionofHydrideAloysandEfectonCyclicPerformanceofNickleMetalHydrideBateries.ibld,45~5625MukerjeeS,McBreenJ,ReilyJJetal.EfectofCeCompositionontheStructuralandElectronicCharacteristicsofSomeMetalHydrideElectrode:AXANESandEXAFSInvestigation.in“Proceedingsofthesymposiumonhydrogenandhydridebateries”editedbyBennettPDandSakaiT.TheElectrochemicalSoc.Inc.,NJ,USA,1994,PV9427,33~4426LatrocheM,PercheronGueganA,ChabreYetal.IntrinsicbehaviouranalysisofsubstitutedLaNi5typeelectrodesbymeansofinsituneutrondifraction.J.AloysandCompounds,1995,231:537~54527SchlapbachL,MeliF,ZuettelA.TheSurfaceofIntermetalicHydrideElectrode.in“Proceedingsofthesymposiumonhydrogenandhydridebateries”editedbyBennettPDandSakaiT.TheElectrochemicalSoc.Inc.,NJ,USA,1994:PV9427,102~11028WangXL,SudaS.“Surfacecharacteristicsoffluorinatedhydridingaloys”.J.AloyandCompounds,1995,231:38029YangY,LiJ,NanJM,LinZG.“PerformanceandCharacterizationofmetalhydrideelectrodesinNiMHbatteries”,Proceedingsof20thInternationalPowerSourcesSymposium(PowerSources16),Elsevier,UK.Acepted30胡蓉晖,杨汉西,卢世刚,李升宪,刘金城,杨聪智.贮氢合金电极的活化方法和作用机理研究.电化学,1996,2:171~17431IwakuaraC,MatsuokaM,AsaiKetal.Surfacemodificationofmetalhydridenegativeelectrodeandtheirchargedischargeperformance.J.PowerSources,1992,192:15532SakaiT,MiyyammaH,KuriyamaNetal.Rareearthbasedhydrogenstoragealoysforrechargeablenicklemetalhydridebatery.J.AloyandCompounds,1993,192:15533KumarMPS,ZhangW,PetrovKetal.EfectofCe,Co,andSnSubstitutiononGasPhaseandElectrochemicalHydride/DehydridingPropertiesofLaNi5.J.Electrochem.Soc.,1995,142:342
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