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Corresponding Author

Yan-xia CHEN(yachen@ustc.edu.cn)

Abstract

This article reviews the recent progress in understanding of the mechanisms for formic acid oxidation on Pt electrode. There are two pathways for formic acid oxidation on Pt electrode: (1) Indirect Pathway through which HCOOH is oxidized to CO2 through COad intermediate. This pathway contributes only 1% of the total current; (2) Direct Pathway where HCOOH is oxidized directly to CO2. The results from IR Spectroscopy, single-crystal electrochemistry and DFT calculation all support that the bridge-bonded formate is neither the intermediate of direct pathway nor the precursor for COad formation in indirect pathway. Possible mechanism in the direct pathway for formic acid oxidation is discussed.

Graphical Abstract

Keywords

formic acid oxidation, platinum electrode, dual-pathway mechanism, indirect pathway, direct pathway, formate pathway

Publication Date

2014-08-28

Online Available Date

2014-01-30

Revised Date

2014-01-22

Received Date

2013-11-13

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