One-Step Co-deposition of ZSM-5/PANI/PSS Electroactive Film and Its Kinetics Characteristics of Electrochemical Control Selective Separation for Pb²⁺ Ions

Authors

Wen-lei QIAO, Department of Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024. China;
Xiao DU, Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, Nanjing University of Science and Technology, Nanjing 210094, China;
Feng-feng GAO, College of Chemistry and Material Engineering, Hunan University of Arts and Science, Changde 415000, Hunan，China;
Jun-lan ZHENG, Department of Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024. China;
Sha-sha LI, Department of Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024. China;
Xiao-gang HAO, Department of Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024. China;Follow

Corresponding Author

Xiao-gang HAO(xghao@tyut.edu.cn)

Abstract

A novel electroactive composite film consisting of ZSM-5/polyaniline/polystyrene sulfonate(ZSM-5/PANI/PSS) was prepared by double pulse one step co-deposition method. The ZSM-5/PANI/PSS composite film was characterized by FT-IR, SEM, XRD, and XPS techniques. The highly crystalline nano-ZSM-5 was synthesized by hydrothermal method, which could be evenly dispersed in aqueous solution by ultrasonic treatment. The synthesis condition of composite film was optimized through changing the pH value of solution. The ZSM-5/PANI/PSS composite film showed higher adsorption capacity for Pb²⁺ ions. Langmuir model was applied to analyze the adsorption process. The adsorption capacity of composite film for Pb²⁺ ions was 235 mg·g^-1. The adsorption kinetics of Pb²⁺ ions could be described properly by the pseudo-first-order kinetic mode.Furthermore, the pseudo-first-order rate constant was determined to be 0.0227 g·mg^-1·min^-1 in ESIX process, which is higher than that of 0.0117 g·mg^-1·min^-1 in IX process. Therefore, the ZSM-5/PANI/PSS composite film is expected to be a promising material in the field of waste treatment.

Graphical Abstract

Keywords

electrochemically switched ion exchange, ZSM-5/PANI/PSS, adsorption selectivity, Pb2+, adsorption kinetics

DOI Link

https://doi.org/10.13208/j.electrochem.170517

Publication Date

2018-04-28

Online Available Date

2017-06-12

Revised Date

2017-06-09

Received Date

2017-05-17

Recommended Citation

Wen-lei QIAO, Xiao DU, Feng-feng GAO, Jun-lan ZHENG, Sha-sha LI, Xiao-gang HAO. One-Step Co-deposition of ZSM-5/PANI/PSS Electroactive Film and Its Kinetics Characteristics of Electrochemical Control Selective Separation for Pb²⁺ Ions[J]. Journal of Electrochemistry, 2018 , 24(2): 143-153.
DOI: 10.13208/j.electrochem.170517
Available at: https://jelectrochem.xmu.edu.cn/journal/vol24/iss2/6

References

[1] Yue C S, Chong K H, Eng C C, et al. Utilization of Infused Tea Leaves for the Removal of Pb²⁺, Fe²⁺ and Cd²⁺ Ions from Aqueous Solution: Equilibrium and Kinetic Studies[J]. Journal of Water Resource and Protection, 2016, 8(5): 568-579.

[2] Jin G P, Xu S Y, Lei P, et al. Electrochemical mediated preparation of chelating polymer brushes at paraffin-impregnated graphite electrode for Pb²⁺ sensing[J]. Electrochimica Acta, 2014, 130: 526-531..

[3] Reddy D H K, Seshaiah, K, Reddy A V R, et al. Biosorption of Pb²⁺ from aqueous solutions by Moringa oleifera bark: Equilibrium and kinetic studies[J]. Journal of of Hazardous Materials, 2010, 174(1/3): 831-838.

[4] Du D, Liu J, Cui X L, et al. One-step electrochemical deposition of a graphene-ZrO₂ nanocomposite: preparation, characterization and application for detection of organophosphorus agents[J]. Journal of Materials Chemistry, 2011, 21(22): 8032-8037.

[5] Tang R, Li Q, Zhai J P , et al. Adsorption of aqueous Hg(II) by a novel poly (aniline-co-o-aminophenol)/mesoporous silica SBA-15 composite[J]. Polymers for Advanced Technologies, 2011, 22(12): 2231-2236.

[6] Du X, Zhang Q, Qiao W L, et al. Controlled self-assembly of oligomers-grafted fibrous polyaniline/single zirconium phosphate nanosheet hybrids with potential-responsive ion exchange properties[J]. Chemical Engineering Journal, 2016, 302: 516-525.

[7] Ma X L (马旭莉), Zhang Q (张权), Du X (杜晓), et al. Selective separation to Pb²⁺ of electrochemically switched Ion exchange Film of α-ZrP/PANI[J]. Rare Metal Materials and Engineering (稀有金属材料与工程), 2016, 45(8): 2139-2145.

[8] Zhang P L, Zheng J L, Wang Z D, et al. An in situ potential-enhanced ion transport system based on FeHCF-PPy/PSS membrane for the removal of Ca²⁺ and Mg²⁺ from dilute aqueous solution[J]. Industrial & Engineering Chemistry Research, 2016, 55(21): 6194-6203.
[9] Du X, Zhang H, Hao X G, et al. Facile preparation of ion-imprinted composite film for selective electrochemical removal of nickel (II) ions [J]. ACS Applied Materials &Interfaces, 2014, 6(12): 9543-9549.

[10] Li N, Li Z J, Yuan J H, et al. Nickel hexacyanoferrate nanoparticles anchored to multiwalled carbon nanotubes with a grafted poly(4-vinylpyridine) linker for electrically switched ion exchange[J]. Electrochimica Acta, 2012, 72:150-156.
[11] KarnjanakomS, Guan G Q, Hao X G. Fabrication of nickel hexacyanoferrate film on carbon fibers by unipolarpulse electrodeposition method for electrochemically switched ion exchange application[J]. Electrochimica Acta, 2014, 139: 36-41.
[12] Mangold K M, Weidlich C, Schuster J, et al. Ion exchange properties and selectivity of PSS in an electrochemically switchable PPy matrix[J]. Journal of Applied Electrochemistry, 2005, 35(12): 1293-1301.
[13] Weidlich C, Mangold K M, Jüttner K. EQCM study of the ion exchange behaviour of polypyrrole with different counterions in different electrolytes[J]. Electrochimica Acta, 2005, 50(7): 1547-1552.
[14] Zhang Q, Du X, Ma X L, et al. Facile preparation of electroactive amorphous α-ZrP/PANI hybrid film for potential-triggered adsorption of Pb²⁺ ions[J]. Journal of Hazardous Materials, 2015, 289(3): 91-100.
[15] Du X, Guan G Q, Hao X G, et al. A novel electroactive λ-MnO₂/PPy/PSS core-shell nanorod coated electrode for selective recovery of lithium ions at low concentration[J].Journal of Materials Chemistry A, 2016, 4(36): 13989-13996.
[16] Wang X X, Shao D D, Hou G S, et al. Uptake of Pb(II) and U(VI) ions from aqueous solutions by the ZSM-5 zeolite[J]. Journal ofMolecular Liquids, 2015, 207: 338-342.
[17] Yang L H(杨丽辉), Gao C H(高长虹), Wang D(王东), et al. Synthesis and adsorption of ZSM-5 zeolite[J]. Journal of Hebei University of Technology(河北工业大学学报), 2010, 5(5): 33-36.
[18] Kaur B, Srivastava R, Satpati B. Ultratrace detection of toxic heavy metal ions found in water bodies using hydroxyapatite supported nanocrystalline ZSM-5 modified electrodes[J].NewJournal of Chemistry, 2015, 39(7): 5137-5149.
[19] Van G R, Sotelo J L, Menendez J M, et al. Anomalou crystallization mechanism in the synthesis of nanocrystalline ZSM-5[J].Microporous and MesoporousMaterials, 2000, 39(1): 135-147.
[20] Milojevic-Rakic M, Janosevic A, Krstic J, et al. Polyaniline and its composites with zeolite ZSM-5 for efficient removal of glyphosate from aqueous solution[J]. Microporous and Mesoporous Materials, 2013, 180: 141-155.
[21] Chu C C, Wang Y W, Wang L, et al. Synthesis and characterization of novel conductive star polymers containing PSS/PANI arms[J]. SyntheticMetals, 2005, 153(1/3): 321-324.
[22] Kaur B, Srivastava R. Simultaneous determination of epinephrine, paracetamol, and folic acid using transition metal ion-exchanged polyaniline-zeolite organic-inorganic hybrid materials[J]. Sensors and Actuators B: Chemical, 2015, 211: 476-488.
[23] Wang X, Shao D, Hou G, et al. Uptake of Pb(II) and U(VI) ions from aqueous solutions by the ZSM-5 zeolite [J]. Journal of Molecular Liquids, 2015, 207: 338-342.
[24] Zhang R R,Qian J,Ye S L, et al. Enhanced electrochemical capacitive performance of "sandwich-like" MWCNTs/PANI/PSS-GRelectrodematerials[J].RSCAdvances, 2016, 6(103): 100954-100961.
[25] Wang X X, Shao D D, Hou G S, et al. Uptake of Pb(II) and U(VI) ions from aqueous solutions by the ZSM-5 zeolite[J]. Journal ofMolecular Liquids, 2015, 207: 338-342.
[26] Rassat S D, Sukamto J H, Orth R J, et al. Development of an electrically switchedion exchange process for selective ion separations[J]. Separation and Purification Technology, 1999, 15(3): 207-222.
[27] Chen R Y(陈如意), Zhang P L(张鹏乐), Hao X G(郝晓刚), et al. Electrochemical removal of low concentration Pb(II) from aqueous solution based on PPy/ZrP/PTCF electrode[J]. Journal of Electrochemistry(电化学), 2015, 4: 344-352.
[28] Monajjemi M. Investigation of langmuir and freundlich adsorption isotherm of Pb²⁺ ions by micro powder of cedar leaf[J]. Journal of Physical & Theoretical Chemistry, 2017, 13(3): 289-296.
[29] Benjamin M M, Leckie J O. Multiple-site adsorption of Cd²⁺, Cu²⁺, Zn²⁺, and Pb²⁺ on amorphous iron oxyhydroxide[J]. Journal of Colloid and Interface Science, 1981, 79(1): 209-221.
[30] Elmchaouri A, Taoufik N, Anouar F, et al. Interaction of Pb²⁺ with NaY zeolite in aqueous solution: Kinetic study and modelling[J]. Journal of Colloid Science and Biotechnology, 2016, 5(2): 157-164.
[31] Taha A A, Shreadah M A, Heiba H F, et al. Validity of egyptian Na-montmorillonite for adsorption of Pb²⁺, Cd²⁺ and Ni²⁺ under acidic conditions: Characterization, isotherm, kinetics, thermodynamics and application study[J]. Asia-Pacific Journal of Chemical Engineering, 2017,12(2): 292-306.