Research Progresses in Improvement for Low Temperature Performance of Lithium-Ion Batteries

Authors

Yue-ru GU, Do-fluoride Chemicals Co., Ltd, Jiaozuo 454150, Henan, China;
Wei-min ZHAO, College of Chemistry and Chemical Engineering/College of energy, Xiamen University, Xiamen 361005, Fujian China;
Chang-hu SU, Do-fluoride Chemicals Co., Ltd, Jiaozuo 454150, Henan, China;
Chuan-jun LUO, Do-Fluoride (Jiaozuo) New Energy Technology CO., Ltd, Jiaozuo 454150, Henan, China);
Zhong-ru ZHANG, College of Chemistry and Chemical Engineering/College of energy, Xiamen University, Xiamen 361005, Fujian China;
Xu-jin XUE, Do-fluoride Chemicals Co., Ltd, Jiaozuo 454150, Henan, China;Follow
Yong YANG, College of Chemistry and Chemical Engineering/College of energy, Xiamen University, Xiamen 361005, Fujian China;Follow

Corresponding Author

Xu-jin XUE(xxj730305@126.com);
Yong YANG(yyang@xmu.edu.cn)

Abstract

Lithium-ion batteries (LIBs) have become a new research hotspot due to their high energy density and long service life. However, the temperature characteristics, especially the poor performance at low temperatures, have seriously limited their wider applications. In this report, the research progresses in the low temperature performance of LIBs are reviewed. The main existing limitations of LIBs at low temperatures were systematically analyzed, and followed by discussion on the recent improvements in low temperature performances by developing novel cathode, electrolyte, and anode materials. The developments for improving the low temperature performance of LIBs are prospected. The three most important factors that influence the low temperature electrochemical performance of LIBs are as follows: 1) a reduced ion conductivity of the electrolyte and solid electrolyte interface (SEI) film formed on the electrode/electrolyte interface; 2) increased charge-transfer resistances at both the cathode and anode electrolyte- electrode interfaces; 3) slow lithium diffusion in the electrodes. The above three points lead to high polarization and lithium deposition, which may cause problems in terms of performance, reliability and safety of the cell. The key point is to provide expedite paths for the transport of lithium ions and electrons at low temperatures. All the influential aspects, such as cathode, electrolyte,and anode, should be considered to improve the low temperature performance of LIBs. The low temperature electrolyte can be obtained by adjusting the relative compositions, and species of the solvent, salt, and additive. The conductivity of electrolyte can be improved by adding low melting point cosolvents and salts. In addition, use of electrolyte additives forming low impedance interface film is one of the most economic and effective methods to improve the low temperature performance. And the structure of electrode materials can be optimized by doping, coating and decreasing the particle size, which can ensure sufficient conductivity and shorten diffusion path length for lithium ions and electrons. Managing the electrolyte and developing electrodes are efficient methods to improve the low temperature performance. Future studies should be focused on achieving high performance lithium-ion battery materials.

Graphical Abstract

Keywords

lithium ion batteries, low temperature performance, anode, electrolyte, cathode

DOI Link

https://doi.org/10.13208/j.electrochem.180145

Publication Date

2018-10-28

Online Available Date

2018-06-13

Revised Date

2018-05-29

Received Date

2018-05-16

Recommended Citation

Yue-ru GU, Wei-min ZHAO, Chang-hu SU, Chuan-jun LUO, Zhong-ru ZHANG, Xu-jin XUE, Yong YANG. Research Progresses in Improvement for Low Temperature Performance of Lithium-Ion Batteries[J]. Journal of Electrochemistry, 2018 , 24(5): 488-496.
DOI: 10.13208/j.electrochem.180145
Available at: https://jelectrochem.xmu.edu.cn/journal/vol24/iss5/7

References

[1] Liivat A, Thomas J, Guo J H, et al. Novel insights into higher capacity from the Li-ion battery cathode material Li₂FeSiO₄[J]. Electrochimica Acta, 2017, 223: 109-114.
[2] Zhao W G, Zheng J M, Zou L F, et al. High voltage operation of Ni-Rich NMC cathodes enabled by stable electrode/electrolyte interphases[J]. Advanced Energy Mater, 2018, 1800297.
[3] Senyshyn A, Mühlbauer M J, Dolotko O, et al. Low-temperature performance of Li-ion batteries: The behavior of lithiated graphite[J]. Journal of Power Sources, 2015, 282: 235-240.
[4] Zhao S X(赵世玺), Guo S T(郭双桃), Zhao J W(赵建伟), et al. Development on low-temperature performance of lithium ion batteries[J]. Journal of the Chinese Ceramic Society(硅酸盐学报), 2016, 44(1): 19-28.
[5] Liu Y(刘英), Li Q H(李秋红), Hu Y L(胡悦丽). Research on low temperature performance of lithium-ion battery[J]. Chinese Journal of Power Sources(电源技术), 2013, 37(2): 321-323.
[6] Zhang J B(张剑波), Su L S(苏来锁), Li X Y(李新宇), et al. Lithium plating identification from degradation behaviors of lithium-ion cells[J]. Journal of Electrochemistry(电化学), 2016, 22(6): 607-616.
[7] Zhao X W, Zhang G Y, Yang L, et al. A new charging mode of Li-ion batteries with LiFePO₄/C composites under low temperature[J]. Journal of Thermal Analysis & Calorimetry, 2011, 104(2): 561-567.
[8] Yan P(严鹏), Hang Z(黄昭), Wu X Y(吴晓燕), et al. Research progress of olivine lithium ion phosphate for lithium-ion battery[J]. Chinese Journal of Power Sources (电源技术), 2015, 39(8): 1764-1767.
[9] Hu D G(胡东阁), Wang Z Z(王张志), Liu J L(刘佳丽), et al. The effect of precursors on performance of LiNi_0.5Co_0.2Mn_0.3O₂ cathode material[J]. Journal of Electrochemistry(电化学), 2013, 19(3): 204-209
[10] Liu C W(刘昌位), Wang Y(王宇), Guo Y Z(郭玉忠), et al. Surface structure and electrochemical performance of ZnO coated LiNi_1/3Co_1/3Mn_1/3O₂[J]. Journal of Electrochemistry (电化学), 2014, 20(1): 60-65.
[11] Cai S W(蔡少伟). Research progress and application of Li-Ni-Co-Mn-O as cathode material for lithium ion battery [J]. Chinese Journal of Power Sources(电源技术), 2013, 37(6): 1065-1068.
[12] Zhou L Z(周罗增), Xu Q J(徐群杰), Tang W P(汤卫平), et al. Research progress of Mn-based lithium-rich cathode materials for Li-ion batteries[J]. Journal of Electrochemistry(电化学), 2015, 21(2):138-144.
[13] Shen Z H(沈重亨), Shen S Y(沈守宇), Lin Z(林舟)， et al. Aqueous solution-evaporation route synthesis and phase structural research of the Li-rich cathode Li_1.23Ni_0.09Co_0.12Mn_0.56O₂ by in-situ XRD[J]. Journal of Electrochemistry (电化学), 2013, 19(6): 537-543.
[14] Hou M Y(侯孟炎), Bao H L(鲍洪亮), Wang K(王珂), et al. Electrochemical and in situ X-ray absorption fine structure study of Li-rich cathode materials[J]. Journal of Electrochemistry (电化学), 2016, 22(3): 288-298.
[15] Rui X H, Jin Y, Feng X Y, et al. A comparative study on the low-temperature performance of LiFePO₄/C and Li₃V₂(PO₄)₃/C cathodes for lithium-ion batteries[J]. Journal of Power Sources, 2011, 196(4): 2109-2114.
[16] Lv D, Wang L, Hu P, et al. Li₂O-B₂O₃-Li₂SO₄ modified LiNi_1/3Co_1/3Mn_1/3O₂ cathode material for enhanced electrochemical performance[J]. Electrochimica Acta, 2017, 247: 803-811
[17] Zeng L J, Gong Q, Liao X Z, et al. Enhanced low-temperature performance of slight Mn-substituted LiFePO₄/C cathode for lithium ion batteries[J]. Chinese Science Bulletin, 2011, 56(12): 1262-1266.
[18] Li G, Zhang Z, Wang R, et al. Effect of trace Al surface doping on the structure, surface chemistry and low temperature performance of LiNi_0.5Co_0.2Mn_0.3O₂, cathode[J]. Electrochimica Acta, 2016, 212: 399-407.
[19] Jin X, Xu Q J, Liu H M, et al. Excellent rate capability of Mg doped Li[Li_0.2Ni_0.13Co_0.13Mn_0.54]O₂ cathode material for lithium-ion battery[J]. Electrochimica Acta, 2014, 136: 19-26.
[20] Gong Z L(龚正良), Zhang W(张炜), Lv D P(吕东平), et al. Application of synchrotron radiation based electrochemical in-situ techniques to study of electrode materials for lithium-ion batteries[J]. Journal of Electrochemistry(电化学), 2013, 19(6): 521-522
[21] Wang Y, Cao G. Developments in nanostructured cathode materials for high-performance lithium-ion batteries[J]. Advanced Materials, 2010, 20(12): 2251-2269.
[22] Zhao N, Li Y, Zhao X, et al. Effect of particle size and purity on the low temperature electrochemical performance of LiFePO₄/C cathode material[J]. Journal of Alloys & Compounds, 2016, 683: 123-132.
[23] Sun H M(孙红梅), Wei J B(韦佳兵), Zhang J R(张佳瑢), et al. Effect of particle size of lithium iron phosphate on discharge performance at low temperature[J]. Chinese Journal of Power Sources(电源技术), 2013, 37(3): 364-369.
[24] Zhao W M, Ji Y J, Zhang Z R, et al. Recent advances in the research of functional electrolyte additives for lithium-ion batteries[J]. Current Opinion in Electrochemistry, 2017, 6(1): 84-91.
[25] Wei L M(韦连梅), Yan X X(燕溪溪), Zhang S N(张素娜), et al. Progress of low-temperature electrolyte for lithium-ion battery[J]. Energy Storage Science and Technology(储能科学与技术), 2017, 6(1): 69-77.
[26] Jones J P, Smart M C, Krause F C, et al. The effect of electrolyte composition on lithium plating during low temperature charging of Li-ion cells[J]. ECS Transactions, 2017, 75(21): 1-11.
[27] Cappetto A, Cao W J, Luo J F, et al. Performance of wide temperature range electrolytes for Li-ion capacitor pouch cells[J]. Journal of Power Sources, 2017, 359: 205-214.
[28] Li Q, Jiao S, Luo L, et al. Wide temperature electrolytes for lithium-ion batteries[J]. ACS Applied Materials & Interfaces, 2017, 9(22): 18826-18835.
[29] Kasprzyk M, Zalewska A, Niedzicki L, et al. Non-crystallizing solvent mixtures and lithium electrolytes for low temperatures[J]. Solid State Ionics, 2017, 308: 22-26.
[30] Dong X L, Guo Z W, Guo Z Y, et al. Organic batteries operated at -70 °C[J]. Joule, 2018, 2(5): 902-903.
[31] Smart M C, Ratnakumar B V, Chin K B, et al. Lithium-ion electrolytes containing ester cosolvents for improved low temperature performance[J]. Journal of the Electrochemical Society, 2010, 157(12): A1361-A1374.
[32] Smart M C, Bugga R V. Lithium ion electrolytes and lithium ion cells with good low temperature performance: US 8920981B2[P]. 2014.
[33] Zhang S S, Xu K, Jow T R. A new approach toward improved low temperature performance of Li-ion battery[J]. Electrochemistry Communications, 2002, 4(11): 928-932.
[34] Li S, Li X, Liu J, et al. A low-temperature electrolyte for lithium-ion batteries[J]. Ionics, 2015, 21(4): 901-907.
[35] Mandal B K, Padhi A K, Zhong S, et al. New low temperature electrolytes with thermal runaway inhibition for lithium-ion rechargeable batteries[J]. Journal of Power Sources, 2006, 162(1): 690-695.
[36] Hamenu L, Lee H S, Latifatu M, et al. Lithium-silica nanosalt as a low-temperature electrolyte additive for lithium-ion batteries[J]. Current Applied Physics, 2016, 16(6): 611-617.
[37] Bian X J(卞锋菊)，Zhang Z R(张忠如), Yang Y(杨勇). Effects of fluoroethylene carbonate additive on low temperature performance of Li-ion batteries[J]. Journal of Electrochemistry(电化学), 2013, 19(4): 355-340.
[38] Liu B, Li B, Guan S. Effect of fluoroethylene carbonate additive on low temperature performance of Li-ion batteries[J]. Electrochemical and Solid-State Letters, 2012, 15(6): A77-A79.
[39] Yang B, Zhang H, Yu L, et al. Lithium difluorophosphate as an additive to improve the low temperature performance of LiNi_0.5Co_0.2Mn_0.3O₂/graphite cells[J]. Electrochi-
mica Acta, 2016, 221: 107-114.
[40] Zhao W M, Zheng G R, Lin M, et al. Toward a stable solid-electrolyte-interfaces on nickel-rich cathodes: LiPO₂F₂ salt-type additive and its working mechanism for LiNi_0.5Mn_0.25Co_0.25O₂ cathodes[J]. Journal of Power Sources, 2018, 380: 149-157.
[41] Liao L, Fang T, Zhou X, et al. Enhancement of low-temperature performance of LiFePO₄, electrode by butyl sultone as electrolyte additive[J]. Solid State Ionics, 2014, 254(4): 27-31.
[42] Jurng S, Park S, Yoon T, et al. Low-temperature performance improvement of graphite electrode by allylsulfide additive and its film-forming mechanism[J]. Journal of the Electrochemical Society, 2016, 163(8): A1798-A1804.
[43] Zhang S S, Xu K, Jow T R. The low temperature performance of Li-ion batteries[J]. Journal of Power Sources, 2003, 115(1): 137-140.
[44] Zhang S S, Xu K, Jow T R. Low temperature performance of graphite electrode in Li-ion cells[J]. Electrochimica Acta, 2002, 48(3): 241-246.
[45] Lüders C V, Zinth V, Erhard S V, et al. Lithium plating in lithium-ion batteries investigated by voltage relaxation and in situ neutron diffraction[J]. Journal of Power Sources, 2017, 342: 17-23.
[46] Zinth V, Lüders C V, Hofmann M, et al. Lithium plating in lithium-ion batteries at sub-ambient temperatures investigated by in situ neutron diffraction[J]. Journal of Power Sources, 2014, 271: 152-159.
[47] Zhang S S, Xu K, Jow T R. Electrochemical impedance study on the low temperature of Li-ion batteries[J]. Electrochimica Acta, 2004, 49(7): 1057-1061.
[48] Zhang L J(张丽津), Peng D C(彭大春), He Y D(何月德), et al. Structure and electrochemical performance of flake graphite anode materials with mildly expanded interlayer by oxidation[J]. Carbon Techniques(炭素技术), 2016, 35(6): 17-22.
[49] Wu Y S, Lee Y H, Yang Z W, et al. Influences of surface fluorination and carbon coating with furan resin in natural graphite as anode in lithium-ion batteries[J]. Journal of Physics & Chemistry of Solids, 2008, 69(2): 376-382.
[50] Zou M, Li J, Wen W W, et al. Silver-incorporated composites of Fe₂O₃, carbon nanofibers as anodes for highperformance lithium batteries[J]. Journal of Power Sources, 2014, 270(4): 468-474.
[51] Li J, Wen W, Xu G, et al. Fe-added Fe₃C carbon nanofibers as anode for Li ion batteries with excellent low-temperature performance[J]. Electrochimica Acta, 2015, 153: 300-305.
[52] Ohta N, Nagaoka K, Hoshi K, et al. Carbon-coated graphite for anode of lithium ion rechargeable batteries: Graphite substrates for carbon coating[J]. Journal of Power Sources, 2009, 194(2): 985-990.
[53] Nobili F, Mancini M, Dsoke S, et al. Low-temperature behavior of graphite-tin composite anodes for Li-ion batteries[J]. Journal of Power Sources, 2010, 195(20): 7090-7097.
[54] Wu Y, Fang S, Jiang Y. Carbon anodes for a lithium secondary battery based on polyacrylonitrile[J]. Journal of Power Sources, 1998, 75(2): 201-206.
[55] Tang Z Y(唐致远), Wu F(吴菲). Study on modification graphite as anode for lithium ion battery[J]. Chinese Journal of Power Sources (电源技术), 2006, 30(2): 155-161.
[56] Huang C K, Sakamoto J S, Wolfenstine J, et al. The limits of low-temperature performance of Li-ion cells[J]. Journal of the Electrochemical Society, 2000, 147(8): 2893-2896.