Abstract
In this study, differential pulse stripping voltammetry was developed for the quantitative detection of levofloxacin hydrochloride indirectly. Levofloxacin hydrochloride contains organic amine, which can be precipitated upon interaction with Zn(SCN)42-. By means of differential pulse stripping voltammetry, the concentration of Zn2+ can be determined using an in-situ formed bismuth film electrode, which allows determining indirectly the amount of levofloxacine hydrochloride. The linearity equation, I = 1.1401c - 0.5309 with the correlative coefficient R = 0.9979, was presented in the experiment. The results showed that this approach is very sensitive, having a limitation of detection of 3.18 × 10-5 μg·mL-1 in a linearity range of 5.0 ~ 60 μg·mL-1.
Graphical Abstract
Keywords
bismuth film electrode, differential pulse stripping voltammetry, levofloxacine hydrochloride, zinc ion, ion-association compound
Publication Date
2019-12-28
Online Available Date
2018-12-26
Revised Date
2018-12-04
Received Date
2018-09-26
Recommended Citation
Zi-ying GUO, Zuo-peng LI, Jiang LI, Jian-guo ZHAO, Feng FENG.
Quantitative Detection of Levofloxacin Hydrochloride by Differential Pulse Stripping Voltammetry with Electrodeposited Bismuth Film Electrodes[J]. Journal of Electrochemistry,
2019
,
25(6): 792-801.
DOI: 10.13208/j.electrochem.180924
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol25/iss6/17
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