In-Situ Raman Spectroscopic Study of Electrochemical Reactions at Single Crystal Surfaces

Authors

Min SU, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China;
Jin-chao DONG, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China;
Jian-feng LI, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China;Follow

Corresponding Author

Jian-feng LI(li@xmu.edu.cn)

Abstract

Since the 1970s, in-situ spectroscopy (Raman, infrared, etc.) has been used to systematically study the electrochemical interfacial reactions which can provide more information about surface reactions and reveal the mechanisms from microscopic view due to its excellent surface sensitivity and energy resolution. With the development of nano-technology, surface-enhanced Raman scattering effect spectroscopy has made rapid progress. Recently, the emergence of SHINERS provides a good in-situ spectroscopic technique for the study of catalytic reactions on single crystal model electrodes with deterministic surface structure. In this paper, we have summarized the application of SHINERS in the study of single crystal interface, and outlined the perspectives of SHINERS research in different fields.

Graphical Abstract

Keywords

shell-isolated nanoparticle-enhanced Raman spectroscopy, spectroelectrochemistry, single crystal electrode, in-situ

DOI Link

https://doi.org/10.13208/j.electrochem.181241

Publication Date

2020-02-28

Online Available Date

2019-03-12

Revised Date

2019-01-30

Received Date

2018-12-04

Recommended Citation

Min SU, Jin-chao DONG, Jian-feng LI. In-Situ Raman Spectroscopic Study of Electrochemical Reactions at Single Crystal Surfaces[J]. Journal of Electrochemistry, 2020 , 26(1): 54-60.
DOI: 10.13208/j.electrochem.181241
Available at: https://jelectrochem.xmu.edu.cn/journal/vol26/iss1/11