Abstract
In this paper, a recently developed single wire-electrode AC probe technology which does not need a reference or counter electrode was employed to investigate the electrochemical corrosion and sacrificial anode protection behaviors of steel and zinc in 3.5wt.% NaCl. With this simple, fast, reliable and stable probe, the instantaneous corrosion rate and accumulated corrosion loss of carbon steel in 3.5wt.% NaCl were measured, and the results revealed that both were greater than those of zinc. Furthermore, the observed different corrosion behaviors between carbon steel and zinc during the immersion could be caused by their different surface films. With the galvanic couple of carbon steel-zinc, the protection efficiency offered by the anode zinc was found to be above 95%, and it increased initially and then decreased with immersion time.
Graphical Abstract
Keywords
single-wire electrode, AC probe technology, impedance spectrum, galvanic couple, corrosion
Publication Date
2020-06-28
Online Available Date
2019-04-18
Revised Date
2019-04-17
Received Date
2019-03-11
Recommended Citation
Zhen-wen ZOU, Da-jiang ZHENG, Zi-ming WANG, Guang-ling SONG, .
Electrochemical Response of A Single Wire-Electrode AC Probe in 3.5wt.% NaCl[J]. Journal of Electrochemistry,
2020
,
26(3): 317-327.
DOI: 10.13208/j.electrochem.190321
Available at:
https://jelectrochem.xmu.edu.cn/journal/vol26/iss3/7
References
[1] Frankel G S, Pitting corrosion of metals - A review of the critical factors[J]. Journal of The Electrochemical Society, 1998,145(6):2186-2198.
[2] Burstein G T, Liu C, Souto R M, et al. Origins of pitting corrosion[J]. Corrosion Engineering Science and Technology, 2004,39(1):25-30.
[3] Duffo G S, Farina S B, Giordano C M. Characterization of solid embeddable reference electrodes for corrosion monitoring in reinforced concrete structures[J]. Electrochimica Acta, 2009,54(3):1010-1020.
[4] Bouazaze H, Huet F, Nogueira R P. A new approach for monitoring corrosion and flow characteristics in oil/brine mixtures[J]. Electrochimica Acta, 2005,50(10):2081-2090.
[5] Gonzalez J A, Miranda J M, Birbilis N, et al. Electrochemical techniques for studying corrosion of reinforcing steel: Limitations and advantages[J]. Corrosion, 2005,61(1):37-50.
[6] Zou Z W, Song G L, Wang Z M, et al. A single wire-electrode AC probe for monitoring instantaneous electrochemical parameters and accumulated change of the electrode[J]. Electrochimica Acta, 2019,321: UNSP134664.
[7] Song G L( 宋光铃), Zou Z W( 邹振文), Wang Z M( 王子明), et al. Electrochemical corrosion testing equipment and electrochemical corrosion testing method[P]. 中国专利,公开日:2019.12.31,公开号:CN108362637B.
[8] Nishimura T, Katayama H, Noda K, et al. Electrochemical behavior of rust formed on carbon steel in a wet/dry environment containing chloride ions[J]. Corrosion, 2000,56(9):935-941.
[9] Corvo F, Minotas J, Delgado J, et al. Changes in atmospheric corrosion rate caused by chloride ions depending on rain regime[J]. Corrosion Science, 2005,47(4):883-892.
[10] Ma Y T, Li Y, Wang F H. Corrosion of low carbon steel in atmospheric environments of different chloride content[J]. Corrosion Science, 2009,51(5):997-1006.
[11] Dong J H( 董俊华), Ke W( 柯伟). The accelerated test of simulated atmospheric corrosion and the rust evolution of low carbon steel[J]. Journal of Electrochemistryl( 电化学), 2009,15(2):170-178.
[12]
Liu Y W, Wang Z Y, Cao G W, et al. Study on corrosion behavior of zinc exposed in coastal-industrial atmospheric environment[J]. Materials Chemistry and Physics, 2017,198:243-249.
doi: 10.1016/j.matchemphys.2017.05.043
URL
[13] Shi S Y( 施善友), Wang B Y( 王本义). The potential - pH diagrams and selection on technological condition[J]. Journal of Hefei University of Technology(Natural Science)l( 合肥工业大学学报(自然科学版)), 1991,14(3):99-106.
[14] Ramanauskas R, Quintana P, Maldonado L, et al. Corrosion resistance and microstructure of electrodeposited Zn and Zn alloy coatings[J]. Surface & Coatings Technology, 1997,92(1/2):16-21.
[15] Spathis P, Poulios I. The corrosion and photocorrosion of zinc and zinc oxide coatings[J]. Corrosion Science, 1995,37(5):673-680.
[16] Song G L. Theoretical analysis of the measurement of polarisation resistance in reinforced concrete[J]. Cement & Concrete Composites, 2000,22(6):407-415.
[17] Jin A J. Cathodic protection effect of reinforced concrete beam specimens with zinc sacrificial anode in marine environment[J]. Advanced Materials Research, 2015,1125:345-349.
[18] Liu A Q( 刘安强), Xiao K( 肖葵), Li X G( 李晓刚), et al. Comparison of corrosion behavior of pure Zn and Zn-Al alloy coating in serious Xisha marine atmosphere environment[J]. Thermal Spray Technologyl( 热喷涂技术), 2015,7(4):46-52.
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